Iridium(III) and Rhodium(III) compounds of dipyridyl-N-alkylimine and dipyridyl-NH-ketimine: Spectral characterization and crystal structure

Pentamethylcyclopentadienyl iridium(III) and rhodium(III) complexes of formulation [( η 5 -C 5 Me 5 )M{(C 5 H 4 N) 2 C =NR)}Cl]PF 6 were prepared by the reaction of [MCl 2 ( η 5 -C 5 Me 5 )] 2 (M = Ir or Rh) with dipyridyl-N-alkylimine ligands, (C 5 H 4 N) 2 C =NR (R = Me or Et) in the presence of N...

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