Frontier Orbitals in Transition-Metal- and Lanthanide-Mediated Reactions

Frontier orbital theory is demonstrated by investigating the appropriately divided parts of transition states, useful for understanding an essential aspect of transition-metal- and lanthanide-mediated reactions. Atomic orbitals are in phase with each other in the outer space of the antibonding orbit...

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Veröffentlicht in:	Bulletin of the Chemical Society of Japan 2017-01, Vol.90 (1), p.22-29
Hauptverfasser:	Ikeda, Hirotaka, Inagaki, Satoshi
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical bonds Chemical reactions Lanthanides Orbitals Transition metals
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description	Frontier orbital theory is demonstrated by investigating the appropriately divided parts of transition states, useful for understanding an essential aspect of transition-metal- and lanthanide-mediated reactions. Atomic orbitals are in phase with each other in the outer space of the antibonding orbitals of the bonds between transition-metal and main-group atoms.
doi_str_mv	10.1246/bcsj.20160234
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source	Oxford University Press Journals All Titles (1996-Current)
subjects	Chemical bonds Chemical reactions Lanthanides Orbitals Transition metals
title	Frontier Orbitals in Transition-Metal- and Lanthanide-Mediated Reactions
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