Frontier Orbitals in Transition-Metal- and Lanthanide-Mediated Reactions

Frontier Orbitals in Transition-Metal- and Lanthanide-Mediated Reactions

Frontier orbital theory is demonstrated by investigating the appropriately divided parts of transition states, useful for understanding an essential aspect of transition-metal- and lanthanide-mediated reactions. Atomic orbitals are in phase with each other in the outer space of the antibonding orbit...

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Veröffentlicht in:Bulletin of the Chemical Society of Japan 2017-01, Vol.90 (1), p.22-29
Hauptverfasser: Ikeda, Hirotaka, Inagaki, Satoshi
Format: Artikel
Sprache:eng
Schlagworte:
Chemical bonds
Chemical reactions
Lanthanides
Orbitals
Transition metals
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Beschreibung
Zusammenfassung:Frontier orbital theory is demonstrated by investigating the appropriately divided parts of transition states, useful for understanding an essential aspect of transition-metal- and lanthanide-mediated reactions. Atomic orbitals are in phase with each other in the outer space of the antibonding orbitals of the bonds between transition-metal and main-group atoms.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.20160234