Synthesis and magnetic properties of Fe substituted hibonite

  We have investigated the synthesis conditions and magnetic properties of Fe substituted hibonite with initial compositions of CaAl12-xFexO19 (0≤x≤12) and CaAl10-xFexO19-δ (0≤x≤10). The Fe doped hibonite can be synthesized at a sintering temperature of 1300˚C. The X-ray diffraction patterns of Fe s...

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Veröffentlicht in:Journal of the Magnetics Society of Japan 2017, Vol.41(2), pp.20-24
Hauptverfasser: Nagumo, H., Watanabe, K., Kakizaki, K., Kamishima, K.
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creator Nagumo, H.
Watanabe, K.
Kakizaki, K.
Kamishima, K.
description   We have investigated the synthesis conditions and magnetic properties of Fe substituted hibonite with initial compositions of CaAl12-xFexO19 (0≤x≤12) and CaAl10-xFexO19-δ (0≤x≤10). The Fe doped hibonite can be synthesized at a sintering temperature of 1300˚C. The X-ray diffraction patterns of Fe substituted hibonite samples are in good agreement with the pattern of hibonite. The lattice parameter increased due to the difference between the radius of Al3+ and that of Fe3+. The magnetization and Curie temperature of the best sample (CaAl2Fe8O19-δ) are 31 emu/g and 290˚C, respectively.
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The Fe doped hibonite can be synthesized at a sintering temperature of 1300˚C. The X-ray diffraction patterns of Fe substituted hibonite samples are in good agreement with the pattern of hibonite. The lattice parameter increased due to the difference between the radius of Al3+ and that of Fe3+. The magnetization and Curie temperature of the best sample (CaAl2Fe8O19-δ) are 31 emu/g and 290˚C, respectively.</description><identifier>ISSN: 1882-2924</identifier><identifier>EISSN: 1882-2932</identifier><identifier>DOI: 10.3379/msjmag.1701R001</identifier><language>eng</language><publisher>Tokyo: The Magnetics Society of Japan</publisher><subject>Curie temperature ; Diffraction patterns ; hexaferrite ; M-type ; Magnetic properties ; Materials substitution ; Synthesis</subject><ispartof>Journal of the Magnetics Society of Japan, 2017, Vol.41(2), pp.20-24</ispartof><rights>2017 The Magnetics Society of Japan</rights><rights>Copyright Japan Science and Technology Agency 2017</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3401-fc0e4144c5543aa2054566584f82fd6152846d8f94122313e3fbc49a2766b4c23</citedby><cites>FETCH-LOGICAL-c3401-fc0e4144c5543aa2054566584f82fd6152846d8f94122313e3fbc49a2766b4c23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,1877,4010,27900,27901,27902</link.rule.ids></links><search><creatorcontrib>Nagumo, H.</creatorcontrib><creatorcontrib>Watanabe, K.</creatorcontrib><creatorcontrib>Kakizaki, K.</creatorcontrib><creatorcontrib>Kamishima, K.</creatorcontrib><title>Synthesis and magnetic properties of Fe substituted hibonite</title><title>Journal of the Magnetics Society of Japan</title><addtitle>J. Magn. Soc. Jpn.</addtitle><description>  We have investigated the synthesis conditions and magnetic properties of Fe substituted hibonite with initial compositions of CaAl12-xFexO19 (0≤x≤12) and CaAl10-xFexO19-δ (0≤x≤10). The Fe doped hibonite can be synthesized at a sintering temperature of 1300˚C. The X-ray diffraction patterns of Fe substituted hibonite samples are in good agreement with the pattern of hibonite. The lattice parameter increased due to the difference between the radius of Al3+ and that of Fe3+. 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subjects Curie temperature
Diffraction patterns
hexaferrite
M-type
Magnetic properties
Materials substitution
Synthesis
title Synthesis and magnetic properties of Fe substituted hibonite
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