Controlled immobilization of palladium nanoparticles in two different fluorinated polymeric aggregate cores and their application in catalysis
Fluoroalkyl end-capped betaine-type cooligomeric nanocomposites-immobilized palladium nanoparticles were prepared by the reactions of palladium chloride with sodium acetate in the presence of sodium chloride and the corresponding fluorinated cooligomers. Outer blocks of poly(2,3,4,5,6-pentafluorosty...
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| Veröffentlicht in: | Colloid and polymer science 2012-05, Vol.290 (7), p.589-597 |
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| creator | Kijima, Tetsushi Javakhishvili, Irakli Jankova, Katja Hvilsted, Søren Kodama, Shun Sugiya, Masashi Sawada, Hideo |
| description | Fluoroalkyl end-capped betaine-type cooligomeric nanocomposites-immobilized palladium nanoparticles were prepared by the reactions of palladium chloride with sodium acetate in the presence of sodium chloride and the corresponding fluorinated cooligomers. Outer blocks of poly(2,3,4,5,6-pentafluorostyrene)-containing ABA-triblock copolymeric nanocomposites-immobilized palladium nanoparticles were prepared by the use of the corresponding block copolymers under similar conditions. TEM images showed that palladium nanoparticles can be immobilized outside the fluorinated cooligomeric nanocomposite cores; in contrast, palladium nanoparticles can be effectively immobilized inside these fluorinated ABA-triblock copolymeric nanocomposite cores. Thus, these two different fluorinated copolymers enabled the controlled immobilization of palladium nanoparticles in the fluorinated nanocomposite cores. These fluorinated nanocomposites-immobilized palladium nanoparticles were also applied to the catalysts for Suzuki-Miyaura cross-coupling reaction, and the different reactivity between these nanocomposites was observed.
Figure
Controlled immobilization of palladium nanoparticles in two different flourinated nanocomposite cores was observed. Palladium nanoparticles were immobilized onto fluorinated betaine-type cooligomeric nanocomposite cores; in contrast, palladium nanoparticles were effectively immobilized inside poly(2,3,4,5-pentafluorostyrene)-containing copolymeric nanocomposite cores. These fluorinated nanocomposites-immobilized palladium nanoparticles were applied to the catalysts for Suzuki-Miyaura cross-coupling reaction |
| doi_str_mv | 10.1007/s00396-011-2567-9 |
| format | Article |
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Figure
Controlled immobilization of palladium nanoparticles in two different flourinated nanocomposite cores was observed. Palladium nanoparticles were immobilized onto fluorinated betaine-type cooligomeric nanocomposite cores; in contrast, palladium nanoparticles were effectively immobilized inside poly(2,3,4,5-pentafluorostyrene)-containing copolymeric nanocomposite cores. These fluorinated nanocomposites-immobilized palladium nanoparticles were applied to the catalysts for Suzuki-Miyaura cross-coupling reaction</description><identifier>ISSN: 0303-402X</identifier><identifier>EISSN: 1435-1536</identifier><identifier>DOI: 10.1007/s00396-011-2567-9</identifier><identifier>CODEN: CPMSB6</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer-Verlag</publisher><subject>Applied sciences ; Catalysis ; Catalysts: preparations and properties ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Composites ; Exact sciences and technology ; Food Science ; Forms of application and semi-finished materials ; General and physical chemistry ; Nanotechnology and Microengineering ; Organic polymers ; Original Contribution ; Physical Chemistry ; Physicochemistry of polymers ; Polymer industry, paints, wood ; Polymer Sciences ; Properties and characterization ; Soft and Granular Matter ; Special properties (catalyst, reagent or carrier) ; Technology of polymers ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><ispartof>Colloid and polymer science, 2012-05, Vol.290 (7), p.589-597</ispartof><rights>Springer-Verlag 2011</rights><rights>2015 INIST-CNRS</rights><rights>Colloid and Polymer Science is a copyright of Springer, 2012.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c383t-311c1844c5ec3c261d96500be4869e89c45485db46b9a4a81ab7964637e61f4d3</citedby><cites>FETCH-LOGICAL-c383t-311c1844c5ec3c261d96500be4869e89c45485db46b9a4a81ab7964637e61f4d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00396-011-2567-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00396-011-2567-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25836080$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Kijima, Tetsushi</creatorcontrib><creatorcontrib>Javakhishvili, Irakli</creatorcontrib><creatorcontrib>Jankova, Katja</creatorcontrib><creatorcontrib>Hvilsted, Søren</creatorcontrib><creatorcontrib>Kodama, Shun</creatorcontrib><creatorcontrib>Sugiya, Masashi</creatorcontrib><creatorcontrib>Sawada, Hideo</creatorcontrib><title>Controlled immobilization of palladium nanoparticles in two different fluorinated polymeric aggregate cores and their application in catalysis</title><title>Colloid and polymer science</title><addtitle>Colloid Polym Sci</addtitle><description>Fluoroalkyl end-capped betaine-type cooligomeric nanocomposites-immobilized palladium nanoparticles were prepared by the reactions of palladium chloride with sodium acetate in the presence of sodium chloride and the corresponding fluorinated cooligomers. Outer blocks of poly(2,3,4,5,6-pentafluorostyrene)-containing ABA-triblock copolymeric nanocomposites-immobilized palladium nanoparticles were prepared by the use of the corresponding block copolymers under similar conditions. TEM images showed that palladium nanoparticles can be immobilized outside the fluorinated cooligomeric nanocomposite cores; in contrast, palladium nanoparticles can be effectively immobilized inside these fluorinated ABA-triblock copolymeric nanocomposite cores. Thus, these two different fluorinated copolymers enabled the controlled immobilization of palladium nanoparticles in the fluorinated nanocomposite cores. These fluorinated nanocomposites-immobilized palladium nanoparticles were also applied to the catalysts for Suzuki-Miyaura cross-coupling reaction, and the different reactivity between these nanocomposites was observed.
Figure
Controlled immobilization of palladium nanoparticles in two different flourinated nanocomposite cores was observed. Palladium nanoparticles were immobilized onto fluorinated betaine-type cooligomeric nanocomposite cores; in contrast, palladium nanoparticles were effectively immobilized inside poly(2,3,4,5-pentafluorostyrene)-containing copolymeric nanocomposite cores. These fluorinated nanocomposites-immobilized palladium nanoparticles were applied to the catalysts for Suzuki-Miyaura cross-coupling reaction</description><subject>Applied sciences</subject><subject>Catalysis</subject><subject>Catalysts: preparations and properties</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Composites</subject><subject>Exact sciences and technology</subject><subject>Food Science</subject><subject>Forms of application and semi-finished materials</subject><subject>General and physical chemistry</subject><subject>Nanotechnology and Microengineering</subject><subject>Organic polymers</subject><subject>Original Contribution</subject><subject>Physical Chemistry</subject><subject>Physicochemistry of polymers</subject><subject>Polymer industry, paints, wood</subject><subject>Polymer Sciences</subject><subject>Properties and characterization</subject><subject>Soft and Granular Matter</subject><subject>Special properties (catalyst, reagent or carrier)</subject><subject>Technology of polymers</subject><subject>Theory of reactions, general kinetics. 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Nomenclature, chemical documentation, computer chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kijima, Tetsushi</creatorcontrib><creatorcontrib>Javakhishvili, Irakli</creatorcontrib><creatorcontrib>Jankova, Katja</creatorcontrib><creatorcontrib>Hvilsted, Søren</creatorcontrib><creatorcontrib>Kodama, Shun</creatorcontrib><creatorcontrib>Sugiya, Masashi</creatorcontrib><creatorcontrib>Sawada, Hideo</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Colloid and polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kijima, Tetsushi</au><au>Javakhishvili, Irakli</au><au>Jankova, Katja</au><au>Hvilsted, Søren</au><au>Kodama, Shun</au><au>Sugiya, Masashi</au><au>Sawada, Hideo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Controlled immobilization of palladium nanoparticles in two different fluorinated polymeric aggregate cores and their application in catalysis</atitle><jtitle>Colloid and polymer science</jtitle><stitle>Colloid Polym Sci</stitle><date>2012-05-01</date><risdate>2012</risdate><volume>290</volume><issue>7</issue><spage>589</spage><epage>597</epage><pages>589-597</pages><issn>0303-402X</issn><eissn>1435-1536</eissn><coden>CPMSB6</coden><abstract>Fluoroalkyl end-capped betaine-type cooligomeric nanocomposites-immobilized palladium nanoparticles were prepared by the reactions of palladium chloride with sodium acetate in the presence of sodium chloride and the corresponding fluorinated cooligomers. Outer blocks of poly(2,3,4,5,6-pentafluorostyrene)-containing ABA-triblock copolymeric nanocomposites-immobilized palladium nanoparticles were prepared by the use of the corresponding block copolymers under similar conditions. TEM images showed that palladium nanoparticles can be immobilized outside the fluorinated cooligomeric nanocomposite cores; in contrast, palladium nanoparticles can be effectively immobilized inside these fluorinated ABA-triblock copolymeric nanocomposite cores. Thus, these two different fluorinated copolymers enabled the controlled immobilization of palladium nanoparticles in the fluorinated nanocomposite cores. These fluorinated nanocomposites-immobilized palladium nanoparticles were also applied to the catalysts for Suzuki-Miyaura cross-coupling reaction, and the different reactivity between these nanocomposites was observed.
Figure
Controlled immobilization of palladium nanoparticles in two different flourinated nanocomposite cores was observed. Palladium nanoparticles were immobilized onto fluorinated betaine-type cooligomeric nanocomposite cores; in contrast, palladium nanoparticles were effectively immobilized inside poly(2,3,4,5-pentafluorostyrene)-containing copolymeric nanocomposite cores. These fluorinated nanocomposites-immobilized palladium nanoparticles were applied to the catalysts for Suzuki-Miyaura cross-coupling reaction</abstract><cop>Berlin/Heidelberg</cop><pub>Springer-Verlag</pub><doi>10.1007/s00396-011-2567-9</doi><tpages>9</tpages></addata></record> |
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| subjects | Applied sciences Catalysis Catalysts: preparations and properties Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Composites Exact sciences and technology Food Science Forms of application and semi-finished materials General and physical chemistry Nanotechnology and Microengineering Organic polymers Original Contribution Physical Chemistry Physicochemistry of polymers Polymer industry, paints, wood Polymer Sciences Properties and characterization Soft and Granular Matter Special properties (catalyst, reagent or carrier) Technology of polymers Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
| title | Controlled immobilization of palladium nanoparticles in two different fluorinated polymeric aggregate cores and their application in catalysis |
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