Strain-Induced Enhancement of Eu^sup 3+^ Emission in Red Phosphor NaMgPO^sub 4^:Eu^sup 3+^, Al^sup 3
(ProQuest: ... denotes formulae and/or non-USASCII text omitted; see image) A series of (NaMgPO4)0.98-x: ..., ... phosphors were prepared by the solid-state method. X-ray powder diffraction results confirm that the samples contain mixture phases of crystals. The doped effect of Al3+ on the photolumi...
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| Veröffentlicht in: | Journal of electronic materials 2017-02, Vol.46 (2), p.911 |
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| creator | Gao, Yong Long, Qiwei Nong, Rong Wang, Tianman Huang, Yingheng Liao, Sen Zhang, Huaxin |
| description | (ProQuest: ... denotes formulae and/or non-USASCII text omitted; see image) A series of (NaMgPO4)0.98-x: ..., ... phosphors were prepared by the solid-state method. X-ray powder diffraction results confirm that the samples contain mixture phases of crystals. The doped effect of Al3+ on the photoluminescence properties of (NaMgPO4)0.98-x: ..., ... phosphors is discussed. The results indicate that two dependent curves of emission relative intensity and strain on Al3+ doping concentration are all Gaussian curves, and a high correlation is observed between emission relative intensity of Eu3+ and strain caused by Al3+. In other words, emission relative intensity of Eu3+ is enhanced with the increase of the strain. The enhanced mechanism of the strain is discussed. In addition, (NaMgPO4)0.98-x: ..., ... phosphors are electric dipole-dominated transition red phosphors. The optimal molar concentration of Al3+ for the samples is 9%, which (NaMgPO4)0.89: ..., ... is a potential candidate as the red-emitting phosphor for ultraviolet-based white light-emitting diodes. |
| doi_str_mv | 10.1007/s11664-016-4950-2 |
| format | Article |
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X-ray powder diffraction results confirm that the samples contain mixture phases of crystals. The doped effect of Al3+ on the photoluminescence properties of (NaMgPO4)0.98-x: ..., ... phosphors is discussed. The results indicate that two dependent curves of emission relative intensity and strain on Al3+ doping concentration are all Gaussian curves, and a high correlation is observed between emission relative intensity of Eu3+ and strain caused by Al3+. In other words, emission relative intensity of Eu3+ is enhanced with the increase of the strain. The enhanced mechanism of the strain is discussed. In addition, (NaMgPO4)0.98-x: ..., ... phosphors are electric dipole-dominated transition red phosphors. The optimal molar concentration of Al3+ for the samples is 9%, which (NaMgPO4)0.89: ..., ... is a potential candidate as the red-emitting phosphor for ultraviolet-based white light-emitting diodes.</description><identifier>ISSN: 0361-5235</identifier><identifier>EISSN: 1543-186X</identifier><identifier>DOI: 10.1007/s11664-016-4950-2</identifier><identifier>CODEN: JECMA5</identifier><language>eng</language><publisher>Warrendale: Springer Nature B.V</publisher><subject>Chemical compounds ; Chemical synthesis ; Luminescence ; Materials science ; Optical properties</subject><ispartof>Journal of electronic materials, 2017-02, Vol.46 (2), p.911</ispartof><rights>Journal of Electronic Materials is a copyright of Springer, 2017.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Gao, Yong</creatorcontrib><creatorcontrib>Long, Qiwei</creatorcontrib><creatorcontrib>Nong, Rong</creatorcontrib><creatorcontrib>Wang, Tianman</creatorcontrib><creatorcontrib>Huang, Yingheng</creatorcontrib><creatorcontrib>Liao, Sen</creatorcontrib><creatorcontrib>Zhang, Huaxin</creatorcontrib><title>Strain-Induced Enhancement of Eu^sup 3+^ Emission in Red Phosphor NaMgPO^sub 4^:Eu^sup 3+^, Al^sup 3</title><title>Journal of electronic materials</title><description>(ProQuest: ... denotes formulae and/or non-USASCII text omitted; see image) A series of (NaMgPO4)0.98-x: ..., ... phosphors were prepared by the solid-state method. X-ray powder diffraction results confirm that the samples contain mixture phases of crystals. The doped effect of Al3+ on the photoluminescence properties of (NaMgPO4)0.98-x: ..., ... phosphors is discussed. The results indicate that two dependent curves of emission relative intensity and strain on Al3+ doping concentration are all Gaussian curves, and a high correlation is observed between emission relative intensity of Eu3+ and strain caused by Al3+. In other words, emission relative intensity of Eu3+ is enhanced with the increase of the strain. The enhanced mechanism of the strain is discussed. In addition, (NaMgPO4)0.98-x: ..., ... phosphors are electric dipole-dominated transition red phosphors. The optimal molar concentration of Al3+ for the samples is 9%, which (NaMgPO4)0.89: ..., ... is a potential candidate as the red-emitting phosphor for ultraviolet-based white light-emitting diodes.</description><subject>Chemical compounds</subject><subject>Chemical synthesis</subject><subject>Luminescence</subject><subject>Materials science</subject><subject>Optical properties</subject><issn>0361-5235</issn><issn>1543-186X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>8G5</sourceid><sourceid>BENPR</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNqNj8FOwkAURSdEE6rwAe5ewhJH3-t0xsLOmBpdKERYsCqpdLAlMFP7Ov9PE03curonuecurhA3hHeE-HDPRMYkEsnIZKZRxgMRkU6UpNRsLkSEypDUsdJDccV8QCRNKUWiXHVtUTv56sqwsyVkrirczp6s68DvIQs5hwbUNIfsVDPX3kHt4KM3l5XnpvItvBdvX8tF731Cks__FrfwePzhkbjcF0e249-8FpPnbP30IpvWfwfL3fbgQ-v6akupTrE_pGL1P-sM-lRKEQ</recordid><startdate>20170201</startdate><enddate>20170201</enddate><creator>Gao, Yong</creator><creator>Long, Qiwei</creator><creator>Nong, Rong</creator><creator>Wang, Tianman</creator><creator>Huang, Yingheng</creator><creator>Liao, Sen</creator><creator>Zhang, Huaxin</creator><general>Springer Nature B.V</general><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8AF</scope><scope>8AO</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>8G5</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M2O</scope><scope>M2P</scope><scope>M7S</scope><scope>MBDVC</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>Q9U</scope><scope>S0X</scope></search><sort><creationdate>20170201</creationdate><title>Strain-Induced Enhancement of Eu^sup 3+^ Emission in Red Phosphor NaMgPO^sub 4^:Eu^sup 3+^, Al^sup 3</title><author>Gao, Yong ; 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see image) A series of (NaMgPO4)0.98-x: ..., ... phosphors were prepared by the solid-state method. X-ray powder diffraction results confirm that the samples contain mixture phases of crystals. The doped effect of Al3+ on the photoluminescence properties of (NaMgPO4)0.98-x: ..., ... phosphors is discussed. The results indicate that two dependent curves of emission relative intensity and strain on Al3+ doping concentration are all Gaussian curves, and a high correlation is observed between emission relative intensity of Eu3+ and strain caused by Al3+. In other words, emission relative intensity of Eu3+ is enhanced with the increase of the strain. The enhanced mechanism of the strain is discussed. In addition, (NaMgPO4)0.98-x: ..., ... phosphors are electric dipole-dominated transition red phosphors. The optimal molar concentration of Al3+ for the samples is 9%, which (NaMgPO4)0.89: ..., ... is a potential candidate as the red-emitting phosphor for ultraviolet-based white light-emitting diodes.</abstract><cop>Warrendale</cop><pub>Springer Nature B.V</pub><doi>10.1007/s11664-016-4950-2</doi></addata></record> |
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| subjects | Chemical compounds Chemical synthesis Luminescence Materials science Optical properties |
| title | Strain-Induced Enhancement of Eu^sup 3+^ Emission in Red Phosphor NaMgPO^sub 4^:Eu^sup 3+^, Al^sup 3 |
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