ChemInform Abstract: Branched Arylalkenes from Cinnamates: Selectivity Inversion in Heck Reactions by Carboxylates as Deciduous Directing Groups

ChemInform Abstract: Branched Arylalkenes from Cinnamates: Selectivity Inversion in Heck Reactions by Carboxylates as Deciduous Directing Groups

A decarboxylative Mizoroki—Heck coupling of aryl halides with cinnamic acids is presented in which the carboxylate group directs the arylation into its β‐position before being tracelessly removed through protodecarboxylation.

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Veröffentlicht in:ChemInform 2016-12, Vol.47 (52), p.no-no
Hauptverfasser: Tang, Jie, Hackenberger, Dagmar, Goossen, Lukas J.
Format: Artikel
Sprache:eng
Schlagworte:
C‐C bond formation
polyphenylalkene derivatives (stilbene derivatives)
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container_title ChemInform
container_volume 47
creator Tang, Jie
Hackenberger, Dagmar
Goossen, Lukas J.
description A decarboxylative Mizoroki—Heck coupling of aryl halides with cinnamic acids is presented in which the carboxylate group directs the arylation into its β‐position before being tracelessly removed through protodecarboxylation.
doi_str_mv 10.1002/chin.201652175
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source Wiley Online Library - AutoHoldings Journals
subjects C‐C bond formation
polyphenylalkene derivatives (stilbene derivatives)
title ChemInform Abstract: Branched Arylalkenes from Cinnamates: Selectivity Inversion in Heck Reactions by Carboxylates as Deciduous Directing Groups
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