ChemInform Abstract: Annulation of Alkynyl Aryl Ethers with Allyl Pivalates to Give 2,3‐Bismethylenechromanes Through Double C—H Bond Cleavage

The treatment of silylethynyloxyarenes with allylic pivalates in the presence of a palladium catalyst leads to efficient C—H bond cleavage in both substrates and a novel annulation reaction to give 2,3‐bismethylenechromanes.

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Veröffentlicht in:ChemInform 2016-11, Vol.47 (48), p.no-no
Hauptverfasser: Minami, Yasunori, Sakai, Megumi, Anami, Tomohiro, Hiyama, Tamejiro
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container_title ChemInform
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creator Minami, Yasunori
Sakai, Megumi
Anami, Tomohiro
Hiyama, Tamejiro
description The treatment of silylethynyloxyarenes with allylic pivalates in the presence of a palladium catalyst leads to efficient C—H bond cleavage in both substrates and a novel annulation reaction to give 2,3‐bismethylenechromanes.
doi_str_mv 10.1002/chin.201648157
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source Wiley Online Library Journals Frontfile Complete
subjects benzopyran derivatives
ring closure reactions, annulation reactions
title ChemInform Abstract: Annulation of Alkynyl Aryl Ethers with Allyl Pivalates to Give 2,3‐Bismethylenechromanes Through Double C—H Bond Cleavage
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