A Nickel(II) Complex as a Homogeneous Electrocatalyst for Water Oxidation at Neutral pH: Dual Role of HPO42− in Catalysis

A new mononuclear nickel complex, featuring two cis‐relative labile sites, is reported as a homogeneous electrocatalyst for water oxidation in a neutral phosphate buffer. The water oxidation catalysis can be initiated at a moderate overpotential of approximately 0.48 V. Mechanistic studies reveal th...

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Veröffentlicht in:	ChemCatChem 2016-10, Vol.8 (20), p.3287-3293
Hauptverfasser:	Wang, Jia-Wei, Zhang, Xiang-Qiong, Huang, Hai-Hua, Lu, Tong-Bu
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis electrocatalysis homogeneous catalyst molecular catalysis Nickel Oxidation water oxidation
Online-Zugang:	Volltext
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