Alternating copolymerization of cyclic germylenes with N-phenyl-p-quinoneimine via oxidation-reduction process

A new 1:1 alternating copolymerization of a five-membered, six-membered, and seven-membered cyclic germylene having a Me 3 Si-N group with N -phenyl- p -quinoneimine has successfully been demonstrated. The germylenes behaved as a reductant monomer whereas N -phenyl- p -quinoneimine as an oxidant mon...

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Veröffentlicht in:Polymer journal 2016-09, Vol.48 (9), p.969-972
Hauptverfasser: Takano, Hiroshi, Hiraishi, Masafumi, Yaguchi, Shigeru, Iwata, Satoru, Shoda, Shin-ichiro, Kobayashi, Shiro
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container_end_page 972
container_issue 9
container_start_page 969
container_title Polymer journal
container_volume 48
creator Takano, Hiroshi
Hiraishi, Masafumi
Yaguchi, Shigeru
Iwata, Satoru
Shoda, Shin-ichiro
Kobayashi, Shiro
description A new 1:1 alternating copolymerization of a five-membered, six-membered, and seven-membered cyclic germylene having a Me 3 Si-N group with N -phenyl- p -quinoneimine has successfully been demonstrated. The germylenes behaved as a reductant monomer whereas N -phenyl- p -quinoneimine as an oxidant monomer to give copolymers ( oxidation-reduction copolymerization ). In contrast to the previous observation that the copolymerization of cyclic germylenes with p -benzoquinone led to the formation of 2:1 periodic copolymers, the present copolymerization using a p -quinoneimine derivative produces all 1:1 alternating copolymers.
doi_str_mv 10.1038/pj.2016.59
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Biomaterials
Bioorganic Chemistry
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Polymer Sciences
Surfaces and Interfaces
Thin Films
title Alternating copolymerization of cyclic germylenes with N-phenyl-p-quinoneimine via oxidation-reduction process
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