ChemInform Abstract: Highly Stereoselective [3 + 2] Cycloadditions of Chiral Palladium‐Containing N1‐1,3‐Dipoles: A Divergent Approach to Enantioenriched Spirooxindoles

A catalytic asymmetric cycloaddition of 1,3‐dipoles, generated in situ by ring‐opening of aziridines, with 3‐methylene‐2‐oxindoles is developed furnishing spirooxindoles in high yields and excellent stereoselectivities.

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2016-08, Vol.47 (36), p.no-no
Hauptverfasser:	Li, Tian‐Ren, Cheng, Bei‐Yi, Fan, Si‐Qi, Wang, Ya‐Ni, Lu, Liang‐Qiu, Xiao, Wen‐Jing
Format:	Artikel
Sprache:	eng
Schlagworte:	catalysis, phase‐transfer catalysis cycloaddition reactions diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) indole derivatives, isoindole derivatives spirocyclic compounds (heterocyclic compounds)
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	A catalytic asymmetric cycloaddition of 1,3‐dipoles, generated in situ by ring‐opening of aziridines, with 3‐methylene‐2‐oxindoles is developed furnishing spirooxindoles in high yields and excellent stereoselectivities.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201636091