Atropoisomerism in Mono- and Diaryl-Substituted 4-Amino-2,6-lutidines

The Suzuki–Miyaura reaction of 4‐amino‐3,5‐dibromo‐2,6‐lutidine with various ortho‐substituted phenylboronic acids resulted in the formation of a series of mono‐ and diarylated lutidines in the form of atropisomers. The absolute stereochemistry of the chiral compounds was established, in some cases,...

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Veröffentlicht in:	European journal of organic chemistry 2016-06, Vol.2016 (17), p.2966-2971
Hauptverfasser:	Górecki, Marcin, Roszkowski, Piotr, Błachut, Dariusz, Maurin, Jan K., Budzianowski, Armand, Frelek, Jadwiga, Czarnocki, Zbigniew
Format:	Artikel
Sprache:	eng
Schlagworte:	Atropisomerism Circular dichroism Cross-coupling Crystal structure Nitrogen heterocycles Palladium
Online-Zugang:	Volltext
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