Limitations of the Removal of Cyanide from Coking Wastewater by Treatment with Hydrogen Peroxide
This research work evaluates the use of hydrogen peroxide for the removal of cyanide from coking wastewater deriving from the washing of gases in coal combustion furnace. The effect of the presence or absence of suspended solids and organic micropollutants on the efficiency of the treatment is analy...
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| creator | Pueyo, N. Rodríguez-Chueca, J. Ovelleiro, J. L. Ormad, M. P. |
| description | This research work evaluates the use of hydrogen peroxide for the removal of cyanide from coking wastewater deriving from the washing of gases in coal combustion furnace. The effect of the presence or absence of suspended solids and organic micropollutants on the efficiency of the treatment is analyzed. Various dosages of hydrogen peroxide (6.5–200 mg/L) were added to both aqueous solution (at pH 10.5) and industrial wastewater (at pH 10.3) samples. The influence of suspended solids in coking wastewater was analyzed by applying a coagulation–flocculation–decantation process before the hydrogen peroxide treatment. The preliminary cyanide removal treatment in aqueous solution showed that the maximum cyanide removal did not exceed 14 % using a mass ratio of hydrogen peroxide to cyanide of 11.6. The maximum cyanide removal obtained in coking wastewater was 47 % with a mass ratio of hydrogen peroxide to cyanide of 12.2 provided that a coagulation–flocculation–decantation pretreatment was applied to remove the suspended solids composed mainly of coal, calcium carbonate, and magnesium carbonate. On the other hand, the cyanide removal treatment in coking wastewater with hydrogen peroxide showed promising results in the removing of different organic micropollutants formed mainly by polycyclic aromatic hydrocarbons and quinolines. |
| doi_str_mv | 10.1007/s11270-016-2915-y |
| format | Article |
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L. ; Ormad, M. P.</creator><creatorcontrib>Pueyo, N. ; Rodríguez-Chueca, J. ; Ovelleiro, J. L. ; Ormad, M. P.</creatorcontrib><description>This research work evaluates the use of hydrogen peroxide for the removal of cyanide from coking wastewater deriving from the washing of gases in coal combustion furnace. The effect of the presence or absence of suspended solids and organic micropollutants on the efficiency of the treatment is analyzed. Various dosages of hydrogen peroxide (6.5–200 mg/L) were added to both aqueous solution (at pH 10.5) and industrial wastewater (at pH 10.3) samples. The influence of suspended solids in coking wastewater was analyzed by applying a coagulation–flocculation–decantation process before the hydrogen peroxide treatment. The preliminary cyanide removal treatment in aqueous solution showed that the maximum cyanide removal did not exceed 14 % using a mass ratio of hydrogen peroxide to cyanide of 11.6. The maximum cyanide removal obtained in coking wastewater was 47 % with a mass ratio of hydrogen peroxide to cyanide of 12.2 provided that a coagulation–flocculation–decantation pretreatment was applied to remove the suspended solids composed mainly of coal, calcium carbonate, and magnesium carbonate. On the other hand, the cyanide removal treatment in coking wastewater with hydrogen peroxide showed promising results in the removing of different organic micropollutants formed mainly by polycyclic aromatic hydrocarbons and quinolines.</description><identifier>ISSN: 0049-6979</identifier><identifier>EISSN: 1573-2932</identifier><identifier>DOI: 10.1007/s11270-016-2915-y</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Activated carbon ; Ammonia ; Analysis ; Aqueous solutions ; Atmospheric Protection/Air Quality Control/Air Pollution ; By products ; Calcium carbonate ; Climate Change/Climate Change Impacts ; Coagulation ; Coal ; Coal-fired power plants ; Coke ; Combustion ; Copper ; Cyanides ; Decomposition ; Earth and Environmental Science ; Efficiency ; Environment ; Environmental monitoring ; Flocculation ; Hydrogen peroxide ; Hydrogeology ; Industrial wastewater ; Magnesium carbonate ; Micropollutants ; Oxidation ; Plating ; Pollutants ; Pollution control ; Polycyclic aromatic hydrocarbons ; Soil Science & Conservation ; Studies ; Suspended solids ; Water Quality/Water Pollution ; Water treatment</subject><ispartof>Water, air, and soil pollution, 2016-07, Vol.227 (7), p.1, Article 222</ispartof><rights>Springer International Publishing Switzerland 2016</rights><rights>COPYRIGHT 2016 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c355t-3d88395b901b03749460743d8608c500faf50fa9302e531f35e492d8cfc54bfe3</citedby><cites>FETCH-LOGICAL-c355t-3d88395b901b03749460743d8608c500faf50fa9302e531f35e492d8cfc54bfe3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11270-016-2915-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11270-016-2915-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Pueyo, N.</creatorcontrib><creatorcontrib>Rodríguez-Chueca, J.</creatorcontrib><creatorcontrib>Ovelleiro, J. L.</creatorcontrib><creatorcontrib>Ormad, M. P.</creatorcontrib><title>Limitations of the Removal of Cyanide from Coking Wastewater by Treatment with Hydrogen Peroxide</title><title>Water, air, and soil pollution</title><addtitle>Water Air Soil Pollut</addtitle><description>This research work evaluates the use of hydrogen peroxide for the removal of cyanide from coking wastewater deriving from the washing of gases in coal combustion furnace. The effect of the presence or absence of suspended solids and organic micropollutants on the efficiency of the treatment is analyzed. Various dosages of hydrogen peroxide (6.5–200 mg/L) were added to both aqueous solution (at pH 10.5) and industrial wastewater (at pH 10.3) samples. The influence of suspended solids in coking wastewater was analyzed by applying a coagulation–flocculation–decantation process before the hydrogen peroxide treatment. The preliminary cyanide removal treatment in aqueous solution showed that the maximum cyanide removal did not exceed 14 % using a mass ratio of hydrogen peroxide to cyanide of 11.6. The maximum cyanide removal obtained in coking wastewater was 47 % with a mass ratio of hydrogen peroxide to cyanide of 12.2 provided that a coagulation–flocculation–decantation pretreatment was applied to remove the suspended solids composed mainly of coal, calcium carbonate, and magnesium carbonate. On the other hand, the cyanide removal treatment in coking wastewater with hydrogen peroxide showed promising results in the removing of different organic micropollutants formed mainly by polycyclic aromatic hydrocarbons and quinolines.</description><subject>Activated carbon</subject><subject>Ammonia</subject><subject>Analysis</subject><subject>Aqueous solutions</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>By products</subject><subject>Calcium carbonate</subject><subject>Climate Change/Climate Change Impacts</subject><subject>Coagulation</subject><subject>Coal</subject><subject>Coal-fired power plants</subject><subject>Coke</subject><subject>Combustion</subject><subject>Copper</subject><subject>Cyanides</subject><subject>Decomposition</subject><subject>Earth and Environmental Science</subject><subject>Efficiency</subject><subject>Environment</subject><subject>Environmental monitoring</subject><subject>Flocculation</subject><subject>Hydrogen peroxide</subject><subject>Hydrogeology</subject><subject>Industrial wastewater</subject><subject>Magnesium carbonate</subject><subject>Micropollutants</subject><subject>Oxidation</subject><subject>Plating</subject><subject>Pollutants</subject><subject>Pollution control</subject><subject>Polycyclic aromatic hydrocarbons</subject><subject>Soil Science & Conservation</subject><subject>Studies</subject><subject>Suspended solids</subject><subject>Water Quality/Water Pollution</subject><subject>Water treatment</subject><issn>0049-6979</issn><issn>1573-2932</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1kE9vGyEQxVGVSnWSfoDekHpeZ1hgdzlaVvNHstSqStQjxbuDQ-oFF3DS_fbB2hxyKSOB3uj9htEj5AuDJQNorxJjdQsVsKaqFZPV9IEsmGx5Ubw-IwsAoapGteoTOU_pCcpRXbsgvzdudNlkF3yiwdL8iPQnjuHZ7E9yPRnvBqQ2hpGuwx_nd_SXSRlfTMZItxO9j2jyiD7TF5cf6e00xLBDT39gDP8Kekk-WrNP-PntvSAP19_u17fV5vvN3Xq1qXouZa740HVcya0CtgXeCiUaaEXpNtD1EsAaK8ulONQoObNcolD10PW2l2JrkV-Qr_PcQwx_j5iyfgrH6MuXmrVKCMlVI4prObt2Zo_aeRtyNH2pAUfXB4_Wlf6qgUaUhFhTADYDfQwpRbT6EN1o4qQZ6FPyek5eF7M-Ja-nwtQzk4rX7zC-W-W_0CvANoX5</recordid><startdate>20160701</startdate><enddate>20160701</enddate><creator>Pueyo, N.</creator><creator>Rodríguez-Chueca, J.</creator><creator>Ovelleiro, J. 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L.</au><au>Ormad, M. P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Limitations of the Removal of Cyanide from Coking Wastewater by Treatment with Hydrogen Peroxide</atitle><jtitle>Water, air, and soil pollution</jtitle><stitle>Water Air Soil Pollut</stitle><date>2016-07-01</date><risdate>2016</risdate><volume>227</volume><issue>7</issue><spage>1</spage><pages>1-</pages><artnum>222</artnum><issn>0049-6979</issn><eissn>1573-2932</eissn><abstract>This research work evaluates the use of hydrogen peroxide for the removal of cyanide from coking wastewater deriving from the washing of gases in coal combustion furnace. The effect of the presence or absence of suspended solids and organic micropollutants on the efficiency of the treatment is analyzed. Various dosages of hydrogen peroxide (6.5–200 mg/L) were added to both aqueous solution (at pH 10.5) and industrial wastewater (at pH 10.3) samples. The influence of suspended solids in coking wastewater was analyzed by applying a coagulation–flocculation–decantation process before the hydrogen peroxide treatment. The preliminary cyanide removal treatment in aqueous solution showed that the maximum cyanide removal did not exceed 14 % using a mass ratio of hydrogen peroxide to cyanide of 11.6. The maximum cyanide removal obtained in coking wastewater was 47 % with a mass ratio of hydrogen peroxide to cyanide of 12.2 provided that a coagulation–flocculation–decantation pretreatment was applied to remove the suspended solids composed mainly of coal, calcium carbonate, and magnesium carbonate. On the other hand, the cyanide removal treatment in coking wastewater with hydrogen peroxide showed promising results in the removing of different organic micropollutants formed mainly by polycyclic aromatic hydrocarbons and quinolines.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s11270-016-2915-y</doi></addata></record> |
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| ispartof | Water, air, and soil pollution, 2016-07, Vol.227 (7), p.1, Article 222 |
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| subjects | Activated carbon Ammonia Analysis Aqueous solutions Atmospheric Protection/Air Quality Control/Air Pollution By products Calcium carbonate Climate Change/Climate Change Impacts Coagulation Coal Coal-fired power plants Coke Combustion Copper Cyanides Decomposition Earth and Environmental Science Efficiency Environment Environmental monitoring Flocculation Hydrogen peroxide Hydrogeology Industrial wastewater Magnesium carbonate Micropollutants Oxidation Plating Pollutants Pollution control Polycyclic aromatic hydrocarbons Soil Science & Conservation Studies Suspended solids Water Quality/Water Pollution Water treatment |
| title | Limitations of the Removal of Cyanide from Coking Wastewater by Treatment with Hydrogen Peroxide |
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