Annealing effect on the shape memory properties of polylactic acid (PLA)/thermoplastic polyurethane (TPU) bio-based blends
PLA and TPU were melt-blended to form shape memory bio-based blends with or without post-annealing effect. To the authors’ best knowledge, this is the first work to discuss the annealing effect on the PLA-based SMP blends. Annealed TPU showed regularly fractured surfaces unlike the macro-phase segre...
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description | PLA and TPU were melt-blended to form shape memory bio-based blends with or without post-annealing effect. To the authors’ best knowledge, this is the first work to discuss the annealing effect on the PLA-based SMP blends. Annealed TPU showed regularly fractured surfaces unlike the macro-phase segregated domains for non-annealed TPU. After 3 h-annealing treatment, spherulites were observed for PLA, but not for TPU. The crystallinity of PLA increased, close to 3-fold increment, for annealed blends in comparison with non-annealed blends. The shape memory behaviors of PLA/TPU blends predeformed under three different predeformation temperatures (25, 80, 120 °C) were investigated. The annealing effect was helpful in enhancing the shape fixing ratio of the PLA/TPU (60/40) blend at high predeformation temperature of 120 °C in comparison with 25 °C. However, the suitable selection of the optimum predeformation temperature at 80 °C outweighed the annealing effect to attain the high shape fixing ratio, even in the case of non-annealed blends. The annealing effect often increased the perfection of crystal domains/interfaces and the larger crystal sizes, which would be detrimental to the molecular extensibility. The overall annealing effect on the shape recovery ratios were quite effective for both PLA/TPU blends of 80/20 and 60/40 without sacrificing the shape fixing ratios at the optimum predeformation temperature of 80 °C, attributing to the increased crystallinity of PLA and homogenized phase domains of TPU. Particularly, the annealing treatment did significantly increase the recovery ratio of the blends, more than 2-fold increment, especially for PLA/TPU (60/40) blend. At both lower or higher predeformation temperatures, the stress concentration between the increased crystalline domains and amorphous regions tended to dominate the annealing effect, leading to a negative contribution to the shape recovery processes. |
doi_str_mv | 10.1007/s10965-016-0993-6 |
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To the authors’ best knowledge, this is the first work to discuss the annealing effect on the PLA-based SMP blends. Annealed TPU showed regularly fractured surfaces unlike the macro-phase segregated domains for non-annealed TPU. After 3 h-annealing treatment, spherulites were observed for PLA, but not for TPU. The crystallinity of PLA increased, close to 3-fold increment, for annealed blends in comparison with non-annealed blends. The shape memory behaviors of PLA/TPU blends predeformed under three different predeformation temperatures (25, 80, 120 °C) were investigated. The annealing effect was helpful in enhancing the shape fixing ratio of the PLA/TPU (60/40) blend at high predeformation temperature of 120 °C in comparison with 25 °C. However, the suitable selection of the optimum predeformation temperature at 80 °C outweighed the annealing effect to attain the high shape fixing ratio, even in the case of non-annealed blends. The annealing effect often increased the perfection of crystal domains/interfaces and the larger crystal sizes, which would be detrimental to the molecular extensibility. The overall annealing effect on the shape recovery ratios were quite effective for both PLA/TPU blends of 80/20 and 60/40 without sacrificing the shape fixing ratios at the optimum predeformation temperature of 80 °C, attributing to the increased crystallinity of PLA and homogenized phase domains of TPU. Particularly, the annealing treatment did significantly increase the recovery ratio of the blends, more than 2-fold increment, especially for PLA/TPU (60/40) blend. At both lower or higher predeformation temperatures, the stress concentration between the increased crystalline domains and amorphous regions tended to dominate the annealing effect, leading to a negative contribution to the shape recovery processes.</description><identifier>ISSN: 1022-9760</identifier><identifier>EISSN: 1572-8935</identifier><identifier>DOI: 10.1007/s10965-016-0993-6</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Industrial Chemistry/Chemical Engineering ; Original Paper ; Polymer Sciences</subject><ispartof>Journal of polymer research, 2016-05, Vol.23 (5), p.1, Article 99</ispartof><rights>Springer Science+Business Media Dordrecht 2016</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-2de9bfabfecdfae1e26a6dc1cf61bfaf849a092f688524fa035d9e5973e2cec43</citedby><cites>FETCH-LOGICAL-c316t-2de9bfabfecdfae1e26a6dc1cf61bfaf849a092f688524fa035d9e5973e2cec43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10965-016-0993-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10965-016-0993-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Lai, Sun-Mou</creatorcontrib><creatorcontrib>Wu, Wan-Ling</creatorcontrib><creatorcontrib>Wang, Yu-Jhen</creatorcontrib><title>Annealing effect on the shape memory properties of polylactic acid (PLA)/thermoplastic polyurethane (TPU) bio-based blends</title><title>Journal of polymer research</title><addtitle>J Polym Res</addtitle><description>PLA and TPU were melt-blended to form shape memory bio-based blends with or without post-annealing effect. To the authors’ best knowledge, this is the first work to discuss the annealing effect on the PLA-based SMP blends. Annealed TPU showed regularly fractured surfaces unlike the macro-phase segregated domains for non-annealed TPU. After 3 h-annealing treatment, spherulites were observed for PLA, but not for TPU. The crystallinity of PLA increased, close to 3-fold increment, for annealed blends in comparison with non-annealed blends. The shape memory behaviors of PLA/TPU blends predeformed under three different predeformation temperatures (25, 80, 120 °C) were investigated. The annealing effect was helpful in enhancing the shape fixing ratio of the PLA/TPU (60/40) blend at high predeformation temperature of 120 °C in comparison with 25 °C. However, the suitable selection of the optimum predeformation temperature at 80 °C outweighed the annealing effect to attain the high shape fixing ratio, even in the case of non-annealed blends. The annealing effect often increased the perfection of crystal domains/interfaces and the larger crystal sizes, which would be detrimental to the molecular extensibility. The overall annealing effect on the shape recovery ratios were quite effective for both PLA/TPU blends of 80/20 and 60/40 without sacrificing the shape fixing ratios at the optimum predeformation temperature of 80 °C, attributing to the increased crystallinity of PLA and homogenized phase domains of TPU. Particularly, the annealing treatment did significantly increase the recovery ratio of the blends, more than 2-fold increment, especially for PLA/TPU (60/40) blend. At both lower or higher predeformation temperatures, the stress concentration between the increased crystalline domains and amorphous regions tended to dominate the annealing effect, leading to a negative contribution to the shape recovery processes.</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Original Paper</subject><subject>Polymer Sciences</subject><issn>1022-9760</issn><issn>1572-8935</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kD1PwzAQhi0EEqXwA9gssbSDqe00TjxWFV9SJTq0s-U45zZVEgc7Hcqvx1EYWJjudPe-9_Eg9MjoM6M0WwRGpUgJZYJQKRMirtCEpRknuUzS65hTzonMBL1FdyGcKE3TTOQT9L1qW9B11R4wWAumx67F_RFwOOoOcAON8xfcedeB7ysI2FncufpSa9NXBmtTlXi23azmi2jyjetqHYbGoDl76I-6BTzbbfdzXFSOFDpAiYsa2jLcoxur6wAPv3GK9q8vu_U72Xy-faxXG2ISJnrCS5CF1UU8rrQaGHChRWmYsYLFus2XUlPJrcjzlC-tpklaSkhllgA3YJbJFD2Nc-MXX2cIvTq5s2_jSsWyPEuoZFE8RWxUGe9C8GBV56tG-4tiVA2I1YhYRcRqQKxE9PDRE6K2PYD_M_lf0w-6XYED</recordid><startdate>20160501</startdate><enddate>20160501</enddate><creator>Lai, Sun-Mou</creator><creator>Wu, Wan-Ling</creator><creator>Wang, Yu-Jhen</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20160501</creationdate><title>Annealing effect on the shape memory properties of polylactic acid (PLA)/thermoplastic polyurethane (TPU) bio-based blends</title><author>Lai, Sun-Mou ; Wu, Wan-Ling ; Wang, Yu-Jhen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-2de9bfabfecdfae1e26a6dc1cf61bfaf849a092f688524fa035d9e5973e2cec43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Original Paper</topic><topic>Polymer Sciences</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lai, Sun-Mou</creatorcontrib><creatorcontrib>Wu, Wan-Ling</creatorcontrib><creatorcontrib>Wang, Yu-Jhen</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials science collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Journal of polymer research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lai, Sun-Mou</au><au>Wu, Wan-Ling</au><au>Wang, Yu-Jhen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Annealing effect on the shape memory properties of polylactic acid (PLA)/thermoplastic polyurethane (TPU) bio-based blends</atitle><jtitle>Journal of polymer research</jtitle><stitle>J Polym Res</stitle><date>2016-05-01</date><risdate>2016</risdate><volume>23</volume><issue>5</issue><spage>1</spage><pages>1-</pages><artnum>99</artnum><issn>1022-9760</issn><eissn>1572-8935</eissn><abstract>PLA and TPU were melt-blended to form shape memory bio-based blends with or without post-annealing effect. To the authors’ best knowledge, this is the first work to discuss the annealing effect on the PLA-based SMP blends. Annealed TPU showed regularly fractured surfaces unlike the macro-phase segregated domains for non-annealed TPU. After 3 h-annealing treatment, spherulites were observed for PLA, but not for TPU. The crystallinity of PLA increased, close to 3-fold increment, for annealed blends in comparison with non-annealed blends. The shape memory behaviors of PLA/TPU blends predeformed under three different predeformation temperatures (25, 80, 120 °C) were investigated. The annealing effect was helpful in enhancing the shape fixing ratio of the PLA/TPU (60/40) blend at high predeformation temperature of 120 °C in comparison with 25 °C. However, the suitable selection of the optimum predeformation temperature at 80 °C outweighed the annealing effect to attain the high shape fixing ratio, even in the case of non-annealed blends. The annealing effect often increased the perfection of crystal domains/interfaces and the larger crystal sizes, which would be detrimental to the molecular extensibility. The overall annealing effect on the shape recovery ratios were quite effective for both PLA/TPU blends of 80/20 and 60/40 without sacrificing the shape fixing ratios at the optimum predeformation temperature of 80 °C, attributing to the increased crystallinity of PLA and homogenized phase domains of TPU. Particularly, the annealing treatment did significantly increase the recovery ratio of the blends, more than 2-fold increment, especially for PLA/TPU (60/40) blend. At both lower or higher predeformation temperatures, the stress concentration between the increased crystalline domains and amorphous regions tended to dominate the annealing effect, leading to a negative contribution to the shape recovery processes.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10965-016-0993-6</doi></addata></record> |
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title | Annealing effect on the shape memory properties of polylactic acid (PLA)/thermoplastic polyurethane (TPU) bio-based blends |
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