Molecular and Electronic Structure of the Cluster [Au8(PPh3)8](NO3)2

We present a detailed structural discussion of [Au8(PPh3)8](NO3)2, crystallized as a CH2Cl2 solvate. Its structure is compared with closely related triphenylphosphine‐stabilized gold clusters. Characterization by optical extinction spectroscopy, luminescence spectroscopy, voltammetry and DFT calcula...

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Veröffentlicht in:	European journal of inorganic chemistry 2016-03, Vol.2016 (7), p.975-981
Hauptverfasser:	Gutrath, Benjamin S., Schiefer, Frank, Homberger, Melanie, Englert, Ulli, Şerb, Mihaela-D., Bettray, Wolfgang, Beljakov, Igor, Meded, Velimir, Wenzel, Wolfgang, Simon, Ulrich
Format:	Artikel
Sprache:	eng
Schlagworte:	Band gap Cluster compounds Electronic structure Gold Nanoparticles Spectrum analysis
Online-Zugang:	Volltext
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