Synthesis of RhIII Anilido, Hydroxide, and Methoxide Complexes
The octahedral RhIII complexes [(tbpy)2Rh(XH)2][OTf]3 (tbpy = 4,4′‐di‐tert‐butyl‐2,2′‐bipyridyl; X = NHPh or OH; OTf = trifluoromethanesulfonate), [(tbpy)2Rh(X)2][OTf] (X = NHPh or OH), [(tbpy)2Rh(NHPh)(NH2Ph)][OTf]2, [(tbpy)2Rh(Me)(NH2Ph)][OTf][BAr′4] (BAr′4 = tetrakis[(3,5‐bis‐trifluoromethyl)phen...
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| Veröffentlicht in: | European journal of inorganic chemistry 2015-02, Vol.2015 (6), p.1041-1052 |
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| container_title | European journal of inorganic chemistry |
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| creator | Burgess, Samantha A. Bolaño, Tamara Gunnoe, T. Brent Sabat, Michal Myers, William H. |
| description | The octahedral RhIII complexes [(tbpy)2Rh(XH)2][OTf]3 (tbpy = 4,4′‐di‐tert‐butyl‐2,2′‐bipyridyl; X = NHPh or OH; OTf = trifluoromethanesulfonate), [(tbpy)2Rh(X)2][OTf] (X = NHPh or OH), [(tbpy)2Rh(NHPh)(NH2Ph)][OTf]2, [(tbpy)2Rh(Me)(NH2Ph)][OTf][BAr′4] (BAr′4 = tetrakis[(3,5‐bis‐trifluoromethyl)phenyl]borate), [(tbpy)2Rh(Me)(NHPh)][BAr′4], [(tbpy)2Rh(OMe)(Cl)]Cl, and [(bpy)Rh(X)2][PF6] (bpy = 2,2′‐bipyridyl; X = OH, OMe) have been synthesized and characterized by 1H, 13C{1H}, and 19F NMR spectroscopy, elemental analysis, or high‐resolution mass spectrometry as well as single‐crystal X‐ray diffraction for some complexes. A comparison of the solid‐state structural data for [(tbpy)2Rh(Me)(NH2Ph)]2+, [(tbpy)2Rh(NH2Ph)2]3+, [(tbpy)2Rh(NHPh)2]+, and [(tbpy)2Rh(NHPh)(NH2Ph)]2+ is included.
Octahedral and d6 complexes with π‐donating ligands often exhibit interesting reactivity. Herein, new examples of RhIII complexes with π‐donating anilido, hydroxide, and methoxide ligands are reported. |
| doi_str_mv | 10.1002/ejic.201403147 |
| format | Article |
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Octahedral and d6 complexes with π‐donating ligands often exhibit interesting reactivity. Herein, new examples of RhIII complexes with π‐donating anilido, hydroxide, and methoxide ligands are reported.</description><identifier>ISSN: 1434-1948</identifier><identifier>EISSN: 1099-0682</identifier><identifier>DOI: 10.1002/ejic.201403147</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Anions ; Crystals ; Diffraction ; Mass spectrometry ; NMR spectroscopy ; Rhodium ; π-Donating ligands</subject><ispartof>European journal of inorganic chemistry, 2015-02, Vol.2015 (6), p.1041-1052</ispartof><rights>Copyright © 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fejic.201403147$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fejic.201403147$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,777,781,1412,27905,27906,45555,45556</link.rule.ids></links><search><creatorcontrib>Burgess, Samantha A.</creatorcontrib><creatorcontrib>Bolaño, Tamara</creatorcontrib><creatorcontrib>Gunnoe, T. Brent</creatorcontrib><creatorcontrib>Sabat, Michal</creatorcontrib><creatorcontrib>Myers, William H.</creatorcontrib><title>Synthesis of RhIII Anilido, Hydroxide, and Methoxide Complexes</title><title>European journal of inorganic chemistry</title><addtitle>Eur. J. Inorg. Chem</addtitle><description>The octahedral RhIII complexes [(tbpy)2Rh(XH)2][OTf]3 (tbpy = 4,4′‐di‐tert‐butyl‐2,2′‐bipyridyl; X = NHPh or OH; OTf = trifluoromethanesulfonate), [(tbpy)2Rh(X)2][OTf] (X = NHPh or OH), [(tbpy)2Rh(NHPh)(NH2Ph)][OTf]2, [(tbpy)2Rh(Me)(NH2Ph)][OTf][BAr′4] (BAr′4 = tetrakis[(3,5‐bis‐trifluoromethyl)phenyl]borate), [(tbpy)2Rh(Me)(NHPh)][BAr′4], [(tbpy)2Rh(OMe)(Cl)]Cl, and [(bpy)Rh(X)2][PF6] (bpy = 2,2′‐bipyridyl; X = OH, OMe) have been synthesized and characterized by 1H, 13C{1H}, and 19F NMR spectroscopy, elemental analysis, or high‐resolution mass spectrometry as well as single‐crystal X‐ray diffraction for some complexes. A comparison of the solid‐state structural data for [(tbpy)2Rh(Me)(NH2Ph)]2+, [(tbpy)2Rh(NH2Ph)2]3+, [(tbpy)2Rh(NHPh)2]+, and [(tbpy)2Rh(NHPh)(NH2Ph)]2+ is included.
Octahedral and d6 complexes with π‐donating ligands often exhibit interesting reactivity. Herein, new examples of RhIII complexes with π‐donating anilido, hydroxide, and methoxide ligands are reported.</description><subject>Anions</subject><subject>Crystals</subject><subject>Diffraction</subject><subject>Mass spectrometry</subject><subject>NMR spectroscopy</subject><subject>Rhodium</subject><subject>π-Donating ligands</subject><issn>1434-1948</issn><issn>1099-0682</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNo9kEFPwkAQhTdGExG9em7ileLsTrttLyakQSiiJojxuFm7Q1gsFLsl0n9vEcNp5iXvm3l5jN1y6HMAcU8rm_cF8ACQB9EZ63BIEh9kLM7bPcDA50kQX7Ir51YAgICywx7emk29JGedVy682TLLMm-wsYU1Zc8bN6Yq99ZQz9Mb4z1TvfyTXlqutwXtyV2zi4UuHN38zy57fxzO07E_fR1l6WDq2zZQ5CNhLA0HLYSJdG60DGPMgSTISHAuFqQx_xSo0RBKQDKGh0JSzomH2kTYZXfHu9uq_N6Rq9Wq3FWb9qXikYxBYCjj1pUcXT-2oEZtK7vWVaM4qENB6lCQOhWkhpMsPamW9Y-sdTXtT6yuvpSMMArVx8tIxbNJ-jRPpwrwF35raZg</recordid><startdate>201502</startdate><enddate>201502</enddate><creator>Burgess, Samantha A.</creator><creator>Bolaño, Tamara</creator><creator>Gunnoe, T. Brent</creator><creator>Sabat, Michal</creator><creator>Myers, William H.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>201502</creationdate><title>Synthesis of RhIII Anilido, Hydroxide, and Methoxide Complexes</title><author>Burgess, Samantha A. ; Bolaño, Tamara ; Gunnoe, T. Brent ; Sabat, Michal ; Myers, William H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i2017-3e386d10a22d7acda6583c0e60672112fea3cb23a3de3603edd1526ec1e15ad73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Anions</topic><topic>Crystals</topic><topic>Diffraction</topic><topic>Mass spectrometry</topic><topic>NMR spectroscopy</topic><topic>Rhodium</topic><topic>π-Donating ligands</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Burgess, Samantha A.</creatorcontrib><creatorcontrib>Bolaño, Tamara</creatorcontrib><creatorcontrib>Gunnoe, T. Brent</creatorcontrib><creatorcontrib>Sabat, Michal</creatorcontrib><creatorcontrib>Myers, William H.</creatorcontrib><collection>Istex</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>European journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Burgess, Samantha A.</au><au>Bolaño, Tamara</au><au>Gunnoe, T. Brent</au><au>Sabat, Michal</au><au>Myers, William H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of RhIII Anilido, Hydroxide, and Methoxide Complexes</atitle><jtitle>European journal of inorganic chemistry</jtitle><addtitle>Eur. J. Inorg. Chem</addtitle><date>2015-02</date><risdate>2015</risdate><volume>2015</volume><issue>6</issue><spage>1041</spage><epage>1052</epage><pages>1041-1052</pages><issn>1434-1948</issn><eissn>1099-0682</eissn><abstract>The octahedral RhIII complexes [(tbpy)2Rh(XH)2][OTf]3 (tbpy = 4,4′‐di‐tert‐butyl‐2,2′‐bipyridyl; X = NHPh or OH; OTf = trifluoromethanesulfonate), [(tbpy)2Rh(X)2][OTf] (X = NHPh or OH), [(tbpy)2Rh(NHPh)(NH2Ph)][OTf]2, [(tbpy)2Rh(Me)(NH2Ph)][OTf][BAr′4] (BAr′4 = tetrakis[(3,5‐bis‐trifluoromethyl)phenyl]borate), [(tbpy)2Rh(Me)(NHPh)][BAr′4], [(tbpy)2Rh(OMe)(Cl)]Cl, and [(bpy)Rh(X)2][PF6] (bpy = 2,2′‐bipyridyl; X = OH, OMe) have been synthesized and characterized by 1H, 13C{1H}, and 19F NMR spectroscopy, elemental analysis, or high‐resolution mass spectrometry as well as single‐crystal X‐ray diffraction for some complexes. A comparison of the solid‐state structural data for [(tbpy)2Rh(Me)(NH2Ph)]2+, [(tbpy)2Rh(NH2Ph)2]3+, [(tbpy)2Rh(NHPh)2]+, and [(tbpy)2Rh(NHPh)(NH2Ph)]2+ is included.
Octahedral and d6 complexes with π‐donating ligands often exhibit interesting reactivity. Herein, new examples of RhIII complexes with π‐donating anilido, hydroxide, and methoxide ligands are reported.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/ejic.201403147</doi><tpages>12</tpages></addata></record> |
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| subjects | Anions Crystals Diffraction Mass spectrometry NMR spectroscopy Rhodium π-Donating ligands |
| title | Synthesis of RhIII Anilido, Hydroxide, and Methoxide Complexes |
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