A Hierarchically Porous Metal-Organic Framework from Semirigid Ligand for Gas Adsorption
Hierarchically porous materials play an important role in facilitating mass transport and improving efficiency of adsorption and separation processes. In this paper, a new strategy is proposed to realize a hierarchically porous metal-organic framework （[Cu2（OH）（L）]＇（DMF）0.8 （FJU-11, H3L=3,5-（4-carbo...
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| Veröffentlicht in: | Chinese journal of chemistry 2016-02, Vol.34 (2), p.215-219 |
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| container_title | Chinese journal of chemistry |
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| creator | Liu, Lizhen Ye, Yingxiang Yao, Zizhu Zhang, Liuqin Li, Ziyin Wang, Lihua Ma, Xiuling Chen, Qian-Huo Zhang, Zhangjing Xiang, Shengchang |
| description | Hierarchically porous materials play an important role in facilitating mass transport and improving efficiency of adsorption and separation processes. In this paper, a new strategy is proposed to realize a hierarchically porous metal-organic framework （[Cu2（OH）（L）]＇（DMF）0.8 （FJU-11, H3L=3,5-（4-carboxybenzyloxy）benzoic acid, DMF= N,N-dimethylformamide） via using semi-rigid multi-carboxylic acids. Interestingly, FJU-11 possesses the large adsorption capacities and small isosteric heats toward CO2. The column breakthrough experiment for FJU-11 highlights its potential application in the separation of the flue gas. |
| doi_str_mv | 10.1002/cjoc.201500617 |
| format | Article |
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In this paper, a new strategy is proposed to realize a hierarchically porous metal-organic framework （[Cu2（OH）（L）]＇（DMF）0.8 （FJU-11, H3L=3,5-（4-carboxybenzyloxy）benzoic acid, DMF= N,N-dimethylformamide） via using semi-rigid multi-carboxylic acids. Interestingly, FJU-11 possesses the large adsorption capacities and small isosteric heats toward CO2. The column breakthrough experiment for FJU-11 highlights its potential application in the separation of the flue gas.</description><identifier>ISSN: 1001-604X</identifier><identifier>EISSN: 1614-7065</identifier><identifier>DOI: 10.1002/cjoc.201500617</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>column breakthrough experiment ; gas sorption ; hierarchical pore ; metal-organic frameworks ; N-二甲基甲酰胺 ; semirigid ligand ; 分离效率 ; 半刚性 ; 多孔材料 ; 框架 ; 气体吸附 ; 配体 ; 金属有机</subject><ispartof>Chinese journal of chemistry, 2016-02, Vol.34 (2), p.215-219</ispartof><rights>Copyright © 2016 SIOC, CAS, Shanghai & WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2016 SIOC, CAS, Shanghai & WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4197-ec52fd5255a15af5d16534e628136000096992d28ab6e264c45324774acdf6333</citedby><cites>FETCH-LOGICAL-c4197-ec52fd5255a15af5d16534e628136000096992d28ab6e264c45324774acdf6333</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/84126X/84126X.jpg</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcjoc.201500617$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcjoc.201500617$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Liu, Lizhen</creatorcontrib><creatorcontrib>Ye, Yingxiang</creatorcontrib><creatorcontrib>Yao, Zizhu</creatorcontrib><creatorcontrib>Zhang, Liuqin</creatorcontrib><creatorcontrib>Li, Ziyin</creatorcontrib><creatorcontrib>Wang, Lihua</creatorcontrib><creatorcontrib>Ma, Xiuling</creatorcontrib><creatorcontrib>Chen, Qian-Huo</creatorcontrib><creatorcontrib>Zhang, Zhangjing</creatorcontrib><creatorcontrib>Xiang, Shengchang</creatorcontrib><title>A Hierarchically Porous Metal-Organic Framework from Semirigid Ligand for Gas Adsorption</title><title>Chinese journal of chemistry</title><addtitle>Chinese Journal of Chemistry</addtitle><description>Hierarchically porous materials play an important role in facilitating mass transport and improving efficiency of adsorption and separation processes. In this paper, a new strategy is proposed to realize a hierarchically porous metal-organic framework （[Cu2（OH）（L）]＇（DMF）0.8 （FJU-11, H3L=3,5-（4-carboxybenzyloxy）benzoic acid, DMF= N,N-dimethylformamide） via using semi-rigid multi-carboxylic acids. Interestingly, FJU-11 possesses the large adsorption capacities and small isosteric heats toward CO2. The column breakthrough experiment for FJU-11 highlights its potential application in the separation of the flue gas.</description><subject>column breakthrough experiment</subject><subject>gas sorption</subject><subject>hierarchical pore</subject><subject>metal-organic frameworks</subject><subject>N-二甲基甲酰胺</subject><subject>semirigid ligand</subject><subject>分离效率</subject><subject>半刚性</subject><subject>多孔材料</subject><subject>框架</subject><subject>气体吸附</subject><subject>配体</subject><subject>金属有机</subject><issn>1001-604X</issn><issn>1614-7065</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkE1vGjEQhldRI5UkvfZsteclttces0eEkqWIhEj9IOrFcrxeMFnWZAyi_Ps4IkK5dS4zh-eZsd8s-8pon1HKr-0q2D6nTFIKTJ1lPQZM5IqC_JRmSlkOVDx-zi5iXCVeKQ697HFIxt6hQbv01rTtgTwEDLtI7tzWtPkMF6bzltyiWbt9wGfSYFiTn27t0S98TaY-ATVpApLKRDKsY8DN1ofuKjtvTBvdl_d-mf2-vfk1GufTWfVjNJzmVrBS5c5K3tSSS2mYNI2sGchCOOADVgBNVUJZ8poPzBM4DsIKWXChlDC2bqAoisvs-3HvBsPLzsWtXoUddumkZgpgkBYISFT_SFkMMaJr9Ab92uBBM6rf0tNv6elTekkoj8Let-7wH1qPJrPRRzc_uj5u3b-Ta_BZgyqU1PP7Spd_5aSa_6n0IPHf3h-3DN3ixXeLk5M-IDkUKZNX3JGMvA</recordid><startdate>201602</startdate><enddate>201602</enddate><creator>Liu, Lizhen</creator><creator>Ye, Yingxiang</creator><creator>Yao, Zizhu</creator><creator>Zhang, Liuqin</creator><creator>Li, Ziyin</creator><creator>Wang, Lihua</creator><creator>Ma, Xiuling</creator><creator>Chen, Qian-Huo</creator><creator>Zhang, Zhangjing</creator><creator>Xiang, Shengchang</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>~WA</scope><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201602</creationdate><title>A Hierarchically Porous Metal-Organic Framework from Semirigid Ligand for Gas Adsorption</title><author>Liu, Lizhen ; Ye, Yingxiang ; Yao, Zizhu ; Zhang, Liuqin ; Li, Ziyin ; Wang, Lihua ; Ma, Xiuling ; Chen, Qian-Huo ; Zhang, Zhangjing ; Xiang, Shengchang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4197-ec52fd5255a15af5d16534e628136000096992d28ab6e264c45324774acdf6333</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>column breakthrough experiment</topic><topic>gas sorption</topic><topic>hierarchical pore</topic><topic>metal-organic frameworks</topic><topic>N-二甲基甲酰胺</topic><topic>semirigid ligand</topic><topic>分离效率</topic><topic>半刚性</topic><topic>多孔材料</topic><topic>框架</topic><topic>气体吸附</topic><topic>配体</topic><topic>金属有机</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Lizhen</creatorcontrib><creatorcontrib>Ye, Yingxiang</creatorcontrib><creatorcontrib>Yao, Zizhu</creatorcontrib><creatorcontrib>Zhang, Liuqin</creatorcontrib><creatorcontrib>Li, Ziyin</creatorcontrib><creatorcontrib>Wang, Lihua</creatorcontrib><creatorcontrib>Ma, Xiuling</creatorcontrib><creatorcontrib>Chen, Qian-Huo</creatorcontrib><creatorcontrib>Zhang, Zhangjing</creatorcontrib><creatorcontrib>Xiang, Shengchang</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库- 镜像站点</collection><collection>Istex</collection><collection>CrossRef</collection><jtitle>Chinese journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Lizhen</au><au>Ye, Yingxiang</au><au>Yao, Zizhu</au><au>Zhang, Liuqin</au><au>Li, Ziyin</au><au>Wang, Lihua</au><au>Ma, Xiuling</au><au>Chen, Qian-Huo</au><au>Zhang, Zhangjing</au><au>Xiang, Shengchang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Hierarchically Porous Metal-Organic Framework from Semirigid Ligand for Gas Adsorption</atitle><jtitle>Chinese journal of chemistry</jtitle><addtitle>Chinese Journal of Chemistry</addtitle><date>2016-02</date><risdate>2016</risdate><volume>34</volume><issue>2</issue><spage>215</spage><epage>219</epage><pages>215-219</pages><issn>1001-604X</issn><eissn>1614-7065</eissn><abstract>Hierarchically porous materials play an important role in facilitating mass transport and improving efficiency of adsorption and separation processes. 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| ispartof | Chinese journal of chemistry, 2016-02, Vol.34 (2), p.215-219 |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | column breakthrough experiment gas sorption hierarchical pore metal-organic frameworks N-二甲基甲酰胺 semirigid ligand 分离效率 半刚性 多孔材料 框架 气体吸附 配体 金属有机 |
| title | A Hierarchically Porous Metal-Organic Framework from Semirigid Ligand for Gas Adsorption |
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