Mn-Based Two Dimensional Metal-Organic Framework Material from Benzimidazole-5,6-dicarboxylic Acid
A new two-dimensional metal-organic framework （MOF） structure has been synthesized by mild solvothermal reaction of MnC12o4H20 with 1H-benzimidazole-5,6-dicarboxylic acid （H3bidc） at 85℃. The structure has been characterized by single-crystal X-ray diffraction, powder X-ray diffraction （PXRD）, infra...
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| Veröffentlicht in: | Chinese journal of chemistry 2016-02, Vol.34 (2), p.233-238 |
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| creator | Zhang, Erpan Zhang, Lili Tan, Zhe Ji, Zhenguo Li, Qiaowei |
| description | A new two-dimensional metal-organic framework （MOF） structure has been synthesized by mild solvothermal reaction of MnC12o4H20 with 1H-benzimidazole-5,6-dicarboxylic acid （H3bidc） at 85℃. The structure has been characterized by single-crystal X-ray diffraction, powder X-ray diffraction （PXRD）, infrared spectroscopy （FT-IR）, and thermogravimetric analysis （TGA）. Single-crystal X-ray diffraction analysis revealed that this MOF is a five-coordinated Mn（II） compound exhibiting a layered 2D network, in which the hydrogen-bonding interactions between uncoordinated carboxylic oxygen atoms and N--H groups in the imidazole rings play a key role in the fi- nal 3D supramolecular architecture. This MOF shows high thermal stability up to 400℃. Furthermore, XRD pattern of the MOF structure was retained for up to 20 d after soaked in water, and only 2.8 wt% of the MOF was decomposed within the first 48 h in water. |
| doi_str_mv | 10.1002/cjoc.201500636 |
| format | Article |
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The structure has been characterized by single-crystal X-ray diffraction, powder X-ray diffraction （PXRD）, infrared spectroscopy （FT-IR）, and thermogravimetric analysis （TGA）. Single-crystal X-ray diffraction analysis revealed that this MOF is a five-coordinated Mn（II） compound exhibiting a layered 2D network, in which the hydrogen-bonding interactions between uncoordinated carboxylic oxygen atoms and N--H groups in the imidazole rings play a key role in the fi- nal 3D supramolecular architecture. This MOF shows high thermal stability up to 400℃. Furthermore, XRD pattern of the MOF structure was retained for up to 20 d after soaked in water, and only 2.8 wt% of the MOF was decomposed within the first 48 h in water.</description><identifier>ISSN: 1001-604X</identifier><identifier>EISSN: 1614-7065</identifier><identifier>DOI: 10.1002/cjoc.201500636</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>6-dicarboxylate ; benzimidazole-5 ; benzimidazole‐5,6‐dicarboxylate ; manganese ; metal-organic framework ; water stability ; X射线粉末衍射 ; 二维网络 ; 二羧酸 ; 单晶X-射线衍射 ; 单晶X射线衍射分析 ; 框架材料 ; 苯并咪唑 ; 金属有机</subject><ispartof>Chinese journal of chemistry, 2016-02, Vol.34 (2), p.233-238</ispartof><rights>Copyright © 2016 SIOC, CAS, Shanghai & WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2016 SIOC, CAS, Shanghai & WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4896-f85b9500da3a5790fcfb417b231fe82ed6c3d0f215b221fab97b4a037ca4e2713</citedby><cites>FETCH-LOGICAL-c4896-f85b9500da3a5790fcfb417b231fe82ed6c3d0f215b221fab97b4a037ca4e2713</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/84126X/84126X.jpg</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcjoc.201500636$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcjoc.201500636$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids></links><search><creatorcontrib>Zhang, Erpan</creatorcontrib><creatorcontrib>Zhang, Lili</creatorcontrib><creatorcontrib>Tan, Zhe</creatorcontrib><creatorcontrib>Ji, Zhenguo</creatorcontrib><creatorcontrib>Li, Qiaowei</creatorcontrib><title>Mn-Based Two Dimensional Metal-Organic Framework Material from Benzimidazole-5,6-dicarboxylic Acid</title><title>Chinese journal of chemistry</title><addtitle>Chinese Journal of Chemistry</addtitle><description>A new two-dimensional metal-organic framework （MOF） structure has been synthesized by mild solvothermal reaction of MnC12o4H20 with 1H-benzimidazole-5,6-dicarboxylic acid （H3bidc） at 85℃. The structure has been characterized by single-crystal X-ray diffraction, powder X-ray diffraction （PXRD）, infrared spectroscopy （FT-IR）, and thermogravimetric analysis （TGA）. Single-crystal X-ray diffraction analysis revealed that this MOF is a five-coordinated Mn（II） compound exhibiting a layered 2D network, in which the hydrogen-bonding interactions between uncoordinated carboxylic oxygen atoms and N--H groups in the imidazole rings play a key role in the fi- nal 3D supramolecular architecture. This MOF shows high thermal stability up to 400℃. Furthermore, XRD pattern of the MOF structure was retained for up to 20 d after soaked in water, and only 2.8 wt% of the MOF was decomposed within the first 48 h in water.</description><subject>6-dicarboxylate</subject><subject>benzimidazole-5</subject><subject>benzimidazole‐5,6‐dicarboxylate</subject><subject>manganese</subject><subject>metal-organic framework</subject><subject>water stability</subject><subject>X射线粉末衍射</subject><subject>二维网络</subject><subject>二羧酸</subject><subject>单晶X-射线衍射</subject><subject>单晶X射线衍射分析</subject><subject>框架材料</subject><subject>苯并咪唑</subject><subject>金属有机</subject><issn>1001-604X</issn><issn>1614-7065</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkEtPAjEURidGExHdup7o1mIfM-3MElHAB-ICg7um02mxODOVFoL46y3BEHeu7l2cc3O_L4rOEewgCPG1nFvZwRClEFJCD6IWoigBDNL0MOwQIkBh8nYcnXg_DzxjmLaiYtSAG-FVGU_WNr41tWq8sY2o4pFaigqM3Uw0RsZ9J2q1tu4jHomlciYA2tk6vlHNt6lNKb5tpUB6RUFppHCF_dpUQetKU55GR1pUXp39znb02r-b9IbgaTy473WfgEyynAKdpUUefi8FESnLoZa6SBArMEFaZViVVJISaozSAmOkRZGzIhGQMCkShRki7ehyd_fT2cVK-SWf25ULUTxHjNIM5qGWQHV2lHTWe6c0_3SmFm7DEeTbHvm2R77vMQj5TlibSm3-oXnvYdz764Kda_xSfe1d4T44ZYSlfPo84I8sG76Q6ZBPA3_x-9y7bWYL08z2TgiQYkpCzh9Qy5Fe</recordid><startdate>201602</startdate><enddate>201602</enddate><creator>Zhang, Erpan</creator><creator>Zhang, Lili</creator><creator>Tan, Zhe</creator><creator>Ji, Zhenguo</creator><creator>Li, Qiaowei</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>~WA</scope><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201602</creationdate><title>Mn-Based Two Dimensional Metal-Organic Framework Material from Benzimidazole-5,6-dicarboxylic Acid</title><author>Zhang, Erpan ; Zhang, Lili ; Tan, Zhe ; Ji, Zhenguo ; Li, Qiaowei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4896-f85b9500da3a5790fcfb417b231fe82ed6c3d0f215b221fab97b4a037ca4e2713</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>6-dicarboxylate</topic><topic>benzimidazole-5</topic><topic>benzimidazole‐5,6‐dicarboxylate</topic><topic>manganese</topic><topic>metal-organic framework</topic><topic>water stability</topic><topic>X射线粉末衍射</topic><topic>二维网络</topic><topic>二羧酸</topic><topic>单晶X-射线衍射</topic><topic>单晶X射线衍射分析</topic><topic>框架材料</topic><topic>苯并咪唑</topic><topic>金属有机</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Erpan</creatorcontrib><creatorcontrib>Zhang, Lili</creatorcontrib><creatorcontrib>Tan, Zhe</creatorcontrib><creatorcontrib>Ji, Zhenguo</creatorcontrib><creatorcontrib>Li, Qiaowei</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库- 镜像站点</collection><collection>Istex</collection><collection>CrossRef</collection><jtitle>Chinese journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Erpan</au><au>Zhang, Lili</au><au>Tan, Zhe</au><au>Ji, Zhenguo</au><au>Li, Qiaowei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mn-Based Two Dimensional Metal-Organic Framework Material from Benzimidazole-5,6-dicarboxylic Acid</atitle><jtitle>Chinese journal of chemistry</jtitle><addtitle>Chinese Journal of Chemistry</addtitle><date>2016-02</date><risdate>2016</risdate><volume>34</volume><issue>2</issue><spage>233</spage><epage>238</epage><pages>233-238</pages><issn>1001-604X</issn><eissn>1614-7065</eissn><abstract>A new two-dimensional metal-organic framework （MOF） structure has been synthesized by mild solvothermal reaction of MnC12o4H20 with 1H-benzimidazole-5,6-dicarboxylic acid （H3bidc） at 85℃. The structure has been characterized by single-crystal X-ray diffraction, powder X-ray diffraction （PXRD）, infrared spectroscopy （FT-IR）, and thermogravimetric analysis （TGA）. Single-crystal X-ray diffraction analysis revealed that this MOF is a five-coordinated Mn（II） compound exhibiting a layered 2D network, in which the hydrogen-bonding interactions between uncoordinated carboxylic oxygen atoms and N--H groups in the imidazole rings play a key role in the fi- nal 3D supramolecular architecture. This MOF shows high thermal stability up to 400℃. Furthermore, XRD pattern of the MOF structure was retained for up to 20 d after soaked in water, and only 2.8 wt% of the MOF was decomposed within the first 48 h in water.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/cjoc.201500636</doi><tpages>6</tpages></addata></record> |
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| subjects | 6-dicarboxylate benzimidazole-5 benzimidazole‐5,6‐dicarboxylate manganese metal-organic framework water stability X射线粉末衍射 二维网络 二羧酸 单晶X-射线衍射 单晶X射线衍射分析 框架材料 苯并咪唑 金属有机 |
| title | Mn-Based Two Dimensional Metal-Organic Framework Material from Benzimidazole-5,6-dicarboxylic Acid |
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