Dioxygen Activation of a Trinuclear CuICuICuI Cluster Capable of Mediating Facile Oxidation of Organic Substrates: Competition between O-Atom Transfer and Abortive Intercomplex Reduction

The dioxygen activation of a series of CuICuICuI complexes based on the ligands (L) 3,3′‐(1,4‐diazepane‐ 1,4‐diyl)bis(1‐{[2‐(dimethylamino)ethyl](methyl)amino}propan‐2‐ol) (7‐Me) or 3,3′‐(1,4‐diazepane‐1,4‐diyl)bis(1‐{[2‐(diethylamino)ethyl](ethyl)amino}propan‐2‐ol) (7‐Et) forms an intermediate capa...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Chemistry : a European journal 2012-03, Vol.18 (13), p.3955-3968
Hauptverfasser:	Maji, Suman, Lee, Jason C.-M., Lu, Yu-Jhang, Chen, Chang-Li, Hung, Mu-Cheng, Chen, Peter P.-Y., Yu, Steve S.-F., Chan, Sunney I.
Format:	Artikel
Sprache:	eng
Schlagworte:	bioinorganic chemistry Chemistry copper enzyme models N,O ligands O ligands OO activation
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!