The Synthesis of (Z)-Trisubstituted Allylic Alcohols by the Selective 1,4-Hydrogenation of Dienol Esters: Improved Synthesis of (-)-[beta]-Santalol

(E)-Trisubstituted allylic alcohols are commonly prepared from the corresponding (E)-enals, themselves readily accessible by a simple aldol condensation reaction. We demonstrate that these very same (E)-enals can be converted into (Z)-trisubstituted allylic acetates (and thus alcohols) by a rutheniu...

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Veröffentlicht in:	Chemistry : a European journal 2011-01, Vol.17 (4), p.1257
Hauptverfasser:	Fehr, Charles, Magpantay, Iris, Vuagnoux, Magali, Dupau, Philippe
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohol Chemistry Hydrogenation
Online-Zugang:	Volltext
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