Chiral Ionic Liquid/ESI-MS Methodology as an Efficient Tool for the Study of Transformations of Supported Organocatalysts: Deactivation Pathways of Jørgensen-Hayashi-Type Catalysts in Asymmetric Michael Reactions

The deactivation pathways of Jørgensen–Hayashi‐type organocatalysts modified with an ionic liquid fragment in asymmetric Michael reactions of α,β‐enals with C‐ (nitromethane, dimethylmalonate) or N‐nucleophiles (N‐carbobenzyloxyhydroxylamine) that involved an iminium‐ion formation step were studied...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Chemistry : a European journal 2011-05, Vol.17 (22), p.6109-6117
Hauptverfasser:	Maltsev, Oleg V., Chizhov, Alexander O., Zlotin, Sergei G.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry ionic liquids mass spectrometry Michael addition organocatalysis reaction mechanisms
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!