Synthesis and Molecular Structure of [beta]-Phosphinoyl Carboxamides: An Unexpected Case of Chiral Discrimination of Hydrogen-Bonded Dimers in the Solid State

A series of N,P,P-trisubstituted aminophosphanes react with diphenylcyclopropenone to afford an easily separable mixture of two diastereomeric [alpha],[beta]-diphenyl-[beta]-phosphinoyl carboxamides in good yields. X-ray crystal structures reveal that these compounds associate into dimers, formed fr...

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Veröffentlicht in:	Chemistry : a European journal 2010-03, Vol.16 (12), p.3728
Hauptverfasser:	Alajarin, Mateo, Lopez-Leonardo, Carmen, Alvarez-Garcia, Ángel, Llamas-Lorente, Pilar, Sanchez-Andrada, Pilar, Berna, José, Pastor, Aurelia, Bautista, Delia, Jones, PeterG
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Crystal structure Discrimination
Online-Zugang:	Volltext
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