Synthesis of Titanium Chabazite: A New Shape Selective Oxidation Catalyst with Small Pore Openings and Application in the Production of Methyl Formate from Methanol

Take CHAnce on zeolites: A new titanium silicate oxidation catalyst (Ti‐CHA) and a bifunctional titanium aluminum silicate catalyst (Ti‐Al‐CHA) with the chabazite (CHA) topology have been synthesized. The materials have a 3‐dimensional channel system with small pore openings that enable shape select...

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Veröffentlicht in:	ChemCatChem 2011-12, Vol.3 (12), p.1869-1871
Hauptverfasser:	Eilertsen, Einar André, Bordiga, Silvia, Lamberti, Carlo, Damin, Alessandro, Bonino, Francesca, Arstad, Bjørnar, Svelle, Stian, Olsbye, Unni, Lillerud, Karl Petter
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Sprache:	eng
Schlagworte:	oxidation silicates titanium topochemistry zeolites
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description	Take CHAnce on zeolites: A new titanium silicate oxidation catalyst (Ti‐CHA) and a bifunctional titanium aluminum silicate catalyst (Ti‐Al‐CHA) with the chabazite (CHA) topology have been synthesized. The materials have a 3‐dimensional channel system with small pore openings that enable shape selective oxidation catalysis. The new Ti‐Al‐CHA material facilitates a high conversion of methanol to methyl formate with a selectivity of 85 % at 60 °C, using H2O2 as the oxidation agent.
doi_str_mv	10.1002/cctc.201100281
format	Article
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subjects	oxidation silicates titanium topochemistry zeolites
title	Synthesis of Titanium Chabazite: A New Shape Selective Oxidation Catalyst with Small Pore Openings and Application in the Production of Methyl Formate from Methanol
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