Zwitterionic Phosphoranides as Intermediates in the Reaction of Phosphorus Tribromide with N,N-Dimethyl-N′-arylformamidines

ABSTRACT Cyclic zwitterionic phosphoranides 2a,b were found to be intermediate products in the reaction of N,N‐dimethyl‐N′‐(aryl)formamidines with PBr3. The structure of phosphoranide 2a was determined by means of the X‐ray and quantum chemistry investigations. Mechanism of its formation was propose...

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Veröffentlicht in:	Heteroatom chemistry 2016-01, Vol.27 (1), p.12-22
Hauptverfasser:	Marchenko, Anatoliy P., Koidan, Georgyi N., Hurieva, Anastasia N., Rozhenko, Alexander B., Kostyuk, Aleksandr N.
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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