Enhanced dielectric and electrorheological properties of needle-like TiO2/polyrhodanine core/shell hybrid nanostructure
ABSTRACT In this study, antisedimentation, dielectric, electrorheological (ER) and creep–recovery properties of needle‐like TiO2/polyrhodanine (PRh) nanocomposite were investigated. Antisedimentation ratio of needle‐like TiO2/PRh was determined to be 45% after 30 days in silicone oil (SO). Polarizab...
Gespeichert in:
| Veröffentlicht in: | Journal of applied polymer science 2016-04, Vol.133 (13), p.n/a |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | n/a |
|---|---|
| container_issue | 13 |
| container_start_page | |
| container_title | Journal of applied polymer science |
| container_volume | 133 |
| creator | Ozkan, Seyma Unal, Halil Ibrahim |
| description | ABSTRACT
In this study, antisedimentation, dielectric, electrorheological (ER) and creep–recovery properties of needle‐like TiO2/polyrhodanine (PRh) nanocomposite were investigated. Antisedimentation ratio of needle‐like TiO2/PRh was determined to be 45% after 30 days in silicone oil (SO). Polarizability and relaxation time of needle‐like TiO2/PRh/SO system were determined to be 0.18 and 2.9 × 10−5 s, respectively by the dielectric spectroscopy which was further used to evaluate the ER performance of the dispersion, and the data obtained were in good agreement with the overall ER results. ER properties of needle‐like TiO2/PRh/SO system were determined by taking the effects of shear rate, shear stress, electric field strength, and temperature into account using a torque electrorheometer. Non‐Newtonian shear thinning behaviors were observed for the samples. Vibration damping capabilities of the dispersions were investigated by measuring their elastic and viscous moduli as functions of frequency, time, and electric field strengths. Enhanced and reversible viscoelastic deformations were recorded for needle‐like TiO2/SO system from creep–recovery tests with 88% recovery under E = 3.5 kV mm−1 condition; thus, the system was classified as a smart one and suitable for potential vibration damping applications. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43240. |
| doi_str_mv | 10.1002/app.43240 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_wiley</sourceid><recordid>TN_cdi_proquest_journals_1757076370</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3922367401</sourcerecordid><originalsourceid>FETCH-LOGICAL-i3310-d0fa0067a14ce68b2850176227d7adb8ee4f064190b982fb375772fbc5b73af33</originalsourceid><addsrcrecordid>eNo9UMtOwzAQtBBIlMKBP7DEOXQdJ3FyrKryUkWpBOJoOfGGGIwdnFTQv8dQxGl2tTM7oyHknMElA0hnqu8vM55mcEAmDCqRZEVaHpJJvLGkrKr8mJwMwysAYzkUE_K5dJ1yDWqqDVpsxmAaqpym-8WHDr31L6ZRlvbB9xhGgwP1LXWI2mJizRvSR7NOZ723u9B5rZxxSBsfcDZ0aC3tdnUwmjrl_DCGbTNuA56So1bZAc_-cEqerpaPi5tktb6-XcxXieGcQaKhVQCFUCxrsCjrtMyBiSJNhRZK1yVi1kKRsQrqqkzbmotciIhNXguuWs6n5GL_N4b_2OIwyle_DS5aSha5IAouILJme9ansbiTfTDvKuwkA_lTqoylyt9S5fzh4XeIimSvMMOIX_8KFd5kIWIK-Xx_LTd3sFpc8Y3c8G_V9H0Y</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1757076370</pqid></control><display><type>article</type><title>Enhanced dielectric and electrorheological properties of needle-like TiO2/polyrhodanine core/shell hybrid nanostructure</title><source>Wiley-Blackwell Journals</source><creator>Ozkan, Seyma ; Unal, Halil Ibrahim</creator><creatorcontrib>Ozkan, Seyma ; Unal, Halil Ibrahim</creatorcontrib><description>ABSTRACT
In this study, antisedimentation, dielectric, electrorheological (ER) and creep–recovery properties of needle‐like TiO2/polyrhodanine (PRh) nanocomposite were investigated. Antisedimentation ratio of needle‐like TiO2/PRh was determined to be 45% after 30 days in silicone oil (SO). Polarizability and relaxation time of needle‐like TiO2/PRh/SO system were determined to be 0.18 and 2.9 × 10−5 s, respectively by the dielectric spectroscopy which was further used to evaluate the ER performance of the dispersion, and the data obtained were in good agreement with the overall ER results. ER properties of needle‐like TiO2/PRh/SO system were determined by taking the effects of shear rate, shear stress, electric field strength, and temperature into account using a torque electrorheometer. Non‐Newtonian shear thinning behaviors were observed for the samples. Vibration damping capabilities of the dispersions were investigated by measuring their elastic and viscous moduli as functions of frequency, time, and electric field strengths. Enhanced and reversible viscoelastic deformations were recorded for needle‐like TiO2/SO system from creep–recovery tests with 88% recovery under E = 3.5 kV mm−1 condition; thus, the system was classified as a smart one and suitable for potential vibration damping applications. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43240.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.43240</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Blackwell Publishing Ltd</publisher><subject>conducting polymers ; dielectric properties ; Materials science ; nanostructured polymers ; Polymers ; rheology ; viscosity and viscoelasticity</subject><ispartof>Journal of applied polymer science, 2016-04, Vol.133 (13), p.n/a</ispartof><rights>2015 Wiley Periodicals, Inc.</rights><rights>2016 Wiley Periodicals, Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.43240$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.43240$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids></links><search><creatorcontrib>Ozkan, Seyma</creatorcontrib><creatorcontrib>Unal, Halil Ibrahim</creatorcontrib><title>Enhanced dielectric and electrorheological properties of needle-like TiO2/polyrhodanine core/shell hybrid nanostructure</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>ABSTRACT
In this study, antisedimentation, dielectric, electrorheological (ER) and creep–recovery properties of needle‐like TiO2/polyrhodanine (PRh) nanocomposite were investigated. Antisedimentation ratio of needle‐like TiO2/PRh was determined to be 45% after 30 days in silicone oil (SO). Polarizability and relaxation time of needle‐like TiO2/PRh/SO system were determined to be 0.18 and 2.9 × 10−5 s, respectively by the dielectric spectroscopy which was further used to evaluate the ER performance of the dispersion, and the data obtained were in good agreement with the overall ER results. ER properties of needle‐like TiO2/PRh/SO system were determined by taking the effects of shear rate, shear stress, electric field strength, and temperature into account using a torque electrorheometer. Non‐Newtonian shear thinning behaviors were observed for the samples. Vibration damping capabilities of the dispersions were investigated by measuring their elastic and viscous moduli as functions of frequency, time, and electric field strengths. Enhanced and reversible viscoelastic deformations were recorded for needle‐like TiO2/SO system from creep–recovery tests with 88% recovery under E = 3.5 kV mm−1 condition; thus, the system was classified as a smart one and suitable for potential vibration damping applications. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43240.</description><subject>conducting polymers</subject><subject>dielectric properties</subject><subject>Materials science</subject><subject>nanostructured polymers</subject><subject>Polymers</subject><subject>rheology</subject><subject>viscosity and viscoelasticity</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNo9UMtOwzAQtBBIlMKBP7DEOXQdJ3FyrKryUkWpBOJoOfGGGIwdnFTQv8dQxGl2tTM7oyHknMElA0hnqu8vM55mcEAmDCqRZEVaHpJJvLGkrKr8mJwMwysAYzkUE_K5dJ1yDWqqDVpsxmAaqpym-8WHDr31L6ZRlvbB9xhGgwP1LXWI2mJizRvSR7NOZ723u9B5rZxxSBsfcDZ0aC3tdnUwmjrl_DCGbTNuA56So1bZAc_-cEqerpaPi5tktb6-XcxXieGcQaKhVQCFUCxrsCjrtMyBiSJNhRZK1yVi1kKRsQrqqkzbmotciIhNXguuWs6n5GL_N4b_2OIwyle_DS5aSha5IAouILJme9ansbiTfTDvKuwkA_lTqoylyt9S5fzh4XeIimSvMMOIX_8KFd5kIWIK-Xx_LTd3sFpc8Y3c8G_V9H0Y</recordid><startdate>20160405</startdate><enddate>20160405</enddate><creator>Ozkan, Seyma</creator><creator>Unal, Halil Ibrahim</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20160405</creationdate><title>Enhanced dielectric and electrorheological properties of needle-like TiO2/polyrhodanine core/shell hybrid nanostructure</title><author>Ozkan, Seyma ; Unal, Halil Ibrahim</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i3310-d0fa0067a14ce68b2850176227d7adb8ee4f064190b982fb375772fbc5b73af33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>conducting polymers</topic><topic>dielectric properties</topic><topic>Materials science</topic><topic>nanostructured polymers</topic><topic>Polymers</topic><topic>rheology</topic><topic>viscosity and viscoelasticity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ozkan, Seyma</creatorcontrib><creatorcontrib>Unal, Halil Ibrahim</creatorcontrib><collection>Istex</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ozkan, Seyma</au><au>Unal, Halil Ibrahim</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhanced dielectric and electrorheological properties of needle-like TiO2/polyrhodanine core/shell hybrid nanostructure</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2016-04-05</date><risdate>2016</risdate><volume>133</volume><issue>13</issue><epage>n/a</epage><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>ABSTRACT
In this study, antisedimentation, dielectric, electrorheological (ER) and creep–recovery properties of needle‐like TiO2/polyrhodanine (PRh) nanocomposite were investigated. Antisedimentation ratio of needle‐like TiO2/PRh was determined to be 45% after 30 days in silicone oil (SO). Polarizability and relaxation time of needle‐like TiO2/PRh/SO system were determined to be 0.18 and 2.9 × 10−5 s, respectively by the dielectric spectroscopy which was further used to evaluate the ER performance of the dispersion, and the data obtained were in good agreement with the overall ER results. ER properties of needle‐like TiO2/PRh/SO system were determined by taking the effects of shear rate, shear stress, electric field strength, and temperature into account using a torque electrorheometer. Non‐Newtonian shear thinning behaviors were observed for the samples. Vibration damping capabilities of the dispersions were investigated by measuring their elastic and viscous moduli as functions of frequency, time, and electric field strengths. Enhanced and reversible viscoelastic deformations were recorded for needle‐like TiO2/SO system from creep–recovery tests with 88% recovery under E = 3.5 kV mm−1 condition; thus, the system was classified as a smart one and suitable for potential vibration damping applications. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43240.</abstract><cop>Hoboken</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/app.43240</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-8995 |
| ispartof | Journal of applied polymer science, 2016-04, Vol.133 (13), p.n/a |
| issn | 0021-8995 1097-4628 |
| language | eng |
| recordid | cdi_proquest_journals_1757076370 |
| source | Wiley-Blackwell Journals |
| subjects | conducting polymers dielectric properties Materials science nanostructured polymers Polymers rheology viscosity and viscoelasticity |
| title | Enhanced dielectric and electrorheological properties of needle-like TiO2/polyrhodanine core/shell hybrid nanostructure |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-24T18%3A03%3A20IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_wiley&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Enhanced%20dielectric%20and%20electrorheological%20properties%20of%20needle-like%20TiO2/polyrhodanine%20core/shell%20hybrid%20nanostructure&rft.jtitle=Journal%20of%20applied%20polymer%20science&rft.au=Ozkan,%20Seyma&rft.date=2016-04-05&rft.volume=133&rft.issue=13&rft.epage=n/a&rft.issn=0021-8995&rft.eissn=1097-4628&rft.coden=JAPNAB&rft_id=info:doi/10.1002/app.43240&rft_dat=%3Cproquest_wiley%3E3922367401%3C/proquest_wiley%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1757076370&rft_id=info:pmid/&rfr_iscdi=true |