First Example of the Intermolecular Palladium-Catalyzed Asymmetric Allylic Alkylation of Hydroxyacrylates: Synthesis of All-Carbon [alpha]-Aryl Quaternary Aldehydes

A set of acyclic all-carbon [alpha]-aryl quaternary aldehydes was synthesized by intermolecular palladium-catalyzed asymmetric allylic alkylation (Pd-AAA). Hydroxyacrylates were used as unprecedented nucleophilic counterparts instead of widely used ketone substrates. This produced a very rare all-ca...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	European journal of organic chemistry 2014-09, Vol.2014 (26), p.5695
Hauptverfasser:	Asad, Sharif A, Ulicki, Joseph, Shevyrev, Maria, Uddin, Nazim, Alberch, Eduardo, Hossain, M Mahmun
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!