Synthesis of trans-A2B2- and trans-A2BC-Porphyrins with Polar 4′-(Dimethylamino)tolan-4-yl Substituents, and a Screening Protocol for Vapor-Phase Deposition on Metal Surfaces

The role of polar 4‐[p‐(dimethylamino)phenylethynyl]phenyl substituents, with a calculated dipole moment of 3.35 Debye, in the self‐assembly of trans‐A2B2‐ and A2BC‐substituted porphyrins was explored in the solid state by X‐ray crystallography, and on an Au(111) surface by scanning tunneling micros...

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Veröffentlicht in:	European journal of organic chemistry 2014-09, Vol.2014 (26), p.5705-5719
Hauptverfasser:	Alberti, Mariza N., Nowakowska, Sylwia, Tzirakis, Manolis D., Nowakowski, Jan, Fesser, Petra, Schweizer, W. Bernd, Shchyrba, Aneliia, Thilgen, Carlo, Jung, Thomas A., Diederich, François
Format:	Artikel
Sprache:	eng
Schlagworte:	Dipole effects Gold Porphyrinoids Self-assembly Supramolecular chemistry Surface analysis
Online-Zugang:	Volltext
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