Trifluoromethylthiolation of Diazo Compounds through Copper Carbene Migratory Insertion

A strategy to introduce the SCF3 group through the CuI‐promoted reaction of diazo compounds with the nucleophilic AgSCF3 trifluoromethylthiolation reagent was developed. Various diazo compounds were smoothly converted under mild conditions to form the C(sp3)–SCF3 bond. Mechanistically, migratory ins...

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Veröffentlicht in:	European journal of organic chemistry 2014-05, Vol.2014 (15), p.3093-3096
Hauptverfasser:	Wang, Xi, Zhou, Yujing, Ji, Guojing, Wu, Guojiao, Li, Ming, Zhang, Yan, Wang, Jianbo
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbenes Diazo compounds Fluorine Migratory insertion
Online-Zugang:	Volltext
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