ChemInform Abstract: Chiral N-(tert-Butyl)-N-methylaniline Type Ligands: Synthesis and Application to Palladium-Catalyzed Asymmetric Allylic Alkylation

The allylic alkylation of malonates with allylic esters is performed in high yields and with very high enantiomeric excess.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2015-12, Vol.46 (51), p.no-no
Hauptverfasser:	Mino, Takashi, Asakawa, Minato, Shima, Yamato, Yamada, Haruka, Yagishita, Fumitoshi, Sakamoto, Masami
Format:	Artikel
Sprache:	eng
Schlagworte:	carboxylic acid esters (acyclic compounds) diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) polyphenylalkene derivatives (stilbene derivatives)
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Beschreibung
Zusammenfassung:	The allylic alkylation of malonates with allylic esters is performed in high yields and with very high enantiomeric excess.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201551070