ChemInform Abstract: Iridium-Catalyzed Borylation of Primary Benzylic C-H Bonds Without a Directing Group: Scope, Mechanism, and Origins of Selectivity

The borylation of methylarenes with a silylborane reagent and a new iridium catalyst containing an electron‐deficient phenanthroline ligand selectively leads to benzylic boronate esters over the corresponding aryl boronate esters.

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Veröffentlicht in:	ChemInform 2015-12, Vol.46 (51), p.no-no
Hauptverfasser:	Larsen, Matthew A., Wilson, Conner V., Hartwig, John F.
Format:	Artikel
Sprache:	eng
Schlagworte:	boration catalysis catalysis, phase‐transfer catalysis hydroboration hydroboration, boration organo-boron compounds phase-transfer catalysis
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description	The borylation of methylarenes with a silylborane reagent and a new iridium catalyst containing an electron‐deficient phenanthroline ligand selectively leads to benzylic boronate esters over the corresponding aryl boronate esters.
doi_str_mv	10.1002/chin.201551175
format	Article
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subjects	boration catalysis catalysis, phase‐transfer catalysis hydroboration hydroboration, boration organo-boron compounds phase-transfer catalysis
title	ChemInform Abstract: Iridium-Catalyzed Borylation of Primary Benzylic C-H Bonds Without a Directing Group: Scope, Mechanism, and Origins of Selectivity
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