ChemInform Abstract: The [beta]-Silyl Effect on the Memory of Chirality in Friedel--Crafts Alkylation Using Chiral [alpha]-Aryl Alcohols

It is found that the retention of the configuration of the hydroxyl group as a leaving group bases on the conformational stability of the carbocation intermediate supported by a flexible silyl substituent.

Bibliographische Detailangaben

Veröffentlicht in:	ChemInform 2015-11, Vol.46 (44)
Hauptverfasser:	Nokami, Toshiki, Yamane, Yu, Oshitani, Shunsuke, Kobayashi, Jun-ka, Matsui, Shin-ichiro, Nishihara, Takashi, Uno, Hidemitsu, Hayase, Shuichi, Itoh, Toshiyuki
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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