Synthesis and NMR Spectroscopic Elucidation of Four Diastereoisomers of Oxygenated Bisabolane Side Chain

Four possible stereoisomers of a model compound of highly O‐bearing bisabolane sesquiterpenes were synthesized and their NMR spectra were compared. Starting from isopulegol, allylic oxidation and Grignard reaction afforded a mixture of alcohols at C(8), which was separated. After metathesis reaction...

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Veröffentlicht in:	Helvetica chimica acta 2015-08, Vol.98 (8), p.1035-1060
Hauptverfasser:	Hirai, Misaki, Miyazaki, Rurina, Mitsui, Kana, Kiuchi, Kota, Onuki, Hiroyuki, Hirota, Hiroshi, Kuroda, Chiaki
Format:	Artikel
Sprache:	eng
Schlagworte:	Bisabolanes NMR NMR Spectroscopy Nuclear magnetic resonance Sesquiterpenoids Spectrum analysis Stereochemistry
Online-Zugang:	Volltext
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