Adsorption of metronidazole in aqueous solution by Fe-modified sepiolite
Metronidazole (MET), a widely used antibiotic, has attracted more attention for its highly solubility, non-biodegradability, and suspected carcinogen. The original sepiolite and its modified counterparts were prepared by different methods and characterized by SEM, XRD, and BET. The specific surface...
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Veröffentlicht in: | Desalination and water treatment 2015-07, Vol.55 (6), p.1620-1628 |
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description | Metronidazole (MET), a widely used antibiotic, has attracted more attention for its highly solubility, non-biodegradability, and suspected carcinogen. The original sepiolite and its modified counterparts were prepared by different methods and characterized by SEM, XRD, and BET. The specific surface area and pore volume of the Fe-modified sepiolite were 217.68 m2/g and 3.8743 cm3/g, respectively, with 19 and 215% increment compared with the original sepiolite. The samples were used to remove MET from aqueous solutions. The effects of pH, contact time, initial MET concentration, and temperature on the adsorption process were investigated. It was found that the Fe-modified sepiolite had higher adsorption capability (36.5%) for MET than that of others. The MET adsorption on the Fe-modified sepiolite was fast and the process conformed to the pseudo-second-order kinetic model, and the adsorption equilibrium data fitted well with the Freundlich isotherms. |
doi_str_mv | 10.1080/19443994.2014.927332 |
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The original sepiolite and its modified counterparts were prepared by different methods and characterized by SEM, XRD, and BET. The specific surface area and pore volume of the Fe-modified sepiolite were 217.68 m2/g and 3.8743 cm3/g, respectively, with 19 and 215% increment compared with the original sepiolite. The samples were used to remove MET from aqueous solutions. The effects of pH, contact time, initial MET concentration, and temperature on the adsorption process were investigated. It was found that the Fe-modified sepiolite had higher adsorption capability (36.5%) for MET than that of others. The MET adsorption on the Fe-modified sepiolite was fast and the process conformed to the pseudo-second-order kinetic model, and the adsorption equilibrium data fitted well with the Freundlich isotherms.</description><identifier>ISSN: 1944-3986</identifier><identifier>ISSN: 1944-3994</identifier><identifier>EISSN: 1944-3986</identifier><identifier>DOI: 10.1080/19443994.2014.927332</identifier><language>eng</language><publisher>Abingdon: Elsevier Inc</publisher><subject>Adsorption ; Aqueous solutions ; Biodegradation ; Fe-modified sepiolite ; Kinetics ; Metronidazole ; Thermodynamics</subject><ispartof>Desalination and water treatment, 2015-07, Vol.55 (6), p.1620-1628</ispartof><rights>2014 Elsevier Inc.</rights><rights>2014 Balaban Desalination Publications. All rights reserved.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c404t-281106534f927cea1ffb657d99a5500603219b9dcc0c37e12cde0496fb80758f3</citedby><cites>FETCH-LOGICAL-c404t-281106534f927cea1ffb657d99a5500603219b9dcc0c37e12cde0496fb80758f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Ding, Hua</creatorcontrib><creatorcontrib>Bian, Guangrong</creatorcontrib><title>Adsorption of metronidazole in aqueous solution by Fe-modified sepiolite</title><title>Desalination and water treatment</title><description>Metronidazole (MET), a widely used antibiotic, has attracted more attention for its highly solubility, non-biodegradability, and suspected carcinogen. The original sepiolite and its modified counterparts were prepared by different methods and characterized by SEM, XRD, and BET. The specific surface area and pore volume of the Fe-modified sepiolite were 217.68 m2/g and 3.8743 cm3/g, respectively, with 19 and 215% increment compared with the original sepiolite. The samples were used to remove MET from aqueous solutions. The effects of pH, contact time, initial MET concentration, and temperature on the adsorption process were investigated. It was found that the Fe-modified sepiolite had higher adsorption capability (36.5%) for MET than that of others. The MET adsorption on the Fe-modified sepiolite was fast and the process conformed to the pseudo-second-order kinetic model, and the adsorption equilibrium data fitted well with the Freundlich isotherms.</description><subject>Adsorption</subject><subject>Aqueous solutions</subject><subject>Biodegradation</subject><subject>Fe-modified sepiolite</subject><subject>Kinetics</subject><subject>Metronidazole</subject><subject>Thermodynamics</subject><issn>1944-3986</issn><issn>1944-3994</issn><issn>1944-3986</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9UMFKxDAQDaLgsu4feAh4bk2apG0uwrK4rrDgRc-hTSaQpdvUpBXWrzdrFTw5lxmG9968eQjdUpJTUpN7KjlnUvK8IJTnsqgYKy7Q4rzOmKzLyz_zNVrFeCCpBK8ELxZotzbRh2F0vsfe4iOMwffONJ--A-x63LxP4KeIo--mb1B7wlvIjt4468DgCIPznRvhBl3Zpouw-ulL9LZ9fN3ssv3L0_Nmvc80J3zMippSUgrGbXKqoaHWtqWojJSNEISUhBVUttJoTTSrgBbaAOGytG1NKlFbtkR3s-4QfPIWR3XwU-jTSUVLWSZVKUVC8Rmlg48xgFVDcMcmnBQl6hyb-o1NnWNTc2yJ9jDTIH3w4SCoqB30GowLoEdlvPtf4As-NXKR</recordid><startdate>20150701</startdate><enddate>20150701</enddate><creator>Ding, Hua</creator><creator>Bian, Guangrong</creator><general>Elsevier Inc</general><general>Elsevier Limited</general><scope>6I.</scope><scope>AAFTH</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7QL</scope><scope>7QO</scope><scope>7ST</scope><scope>7T7</scope><scope>7TN</scope><scope>7UA</scope><scope>8FD</scope><scope>C1K</scope><scope>F1W</scope><scope>FR3</scope><scope>H96</scope><scope>H97</scope><scope>KR7</scope><scope>L.G</scope><scope>M7N</scope><scope>P64</scope><scope>SOI</scope></search><sort><creationdate>20150701</creationdate><title>Adsorption of metronidazole in aqueous solution by Fe-modified sepiolite</title><author>Ding, Hua ; Bian, Guangrong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c404t-281106534f927cea1ffb657d99a5500603219b9dcc0c37e12cde0496fb80758f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Adsorption</topic><topic>Aqueous solutions</topic><topic>Biodegradation</topic><topic>Fe-modified sepiolite</topic><topic>Kinetics</topic><topic>Metronidazole</topic><topic>Thermodynamics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ding, Hua</creatorcontrib><creatorcontrib>Bian, Guangrong</creatorcontrib><collection>ScienceDirect Open Access Titles</collection><collection>Elsevier:ScienceDirect:Open Access</collection><collection>CrossRef</collection><collection>Aqualine</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Biotechnology Research Abstracts</collection><collection>Environment Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Oceanic Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Engineering Research Database</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality</collection><collection>Civil Engineering Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Algology Mycology and Protozoology Abstracts (Microbiology C)</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environment Abstracts</collection><jtitle>Desalination and water treatment</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ding, Hua</au><au>Bian, Guangrong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Adsorption of metronidazole in aqueous solution by Fe-modified sepiolite</atitle><jtitle>Desalination and water treatment</jtitle><date>2015-07-01</date><risdate>2015</risdate><volume>55</volume><issue>6</issue><spage>1620</spage><epage>1628</epage><pages>1620-1628</pages><issn>1944-3986</issn><issn>1944-3994</issn><eissn>1944-3986</eissn><abstract>Metronidazole (MET), a widely used antibiotic, has attracted more attention for its highly solubility, non-biodegradability, and suspected carcinogen. The original sepiolite and its modified counterparts were prepared by different methods and characterized by SEM, XRD, and BET. The specific surface area and pore volume of the Fe-modified sepiolite were 217.68 m2/g and 3.8743 cm3/g, respectively, with 19 and 215% increment compared with the original sepiolite. The samples were used to remove MET from aqueous solutions. The effects of pH, contact time, initial MET concentration, and temperature on the adsorption process were investigated. It was found that the Fe-modified sepiolite had higher adsorption capability (36.5%) for MET than that of others. The MET adsorption on the Fe-modified sepiolite was fast and the process conformed to the pseudo-second-order kinetic model, and the adsorption equilibrium data fitted well with the Freundlich isotherms.</abstract><cop>Abingdon</cop><pub>Elsevier Inc</pub><doi>10.1080/19443994.2014.927332</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Adsorption Aqueous solutions Biodegradation Fe-modified sepiolite Kinetics Metronidazole Thermodynamics |
title | Adsorption of metronidazole in aqueous solution by Fe-modified sepiolite |
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