Double C-H Functionalization to Construct Polycyclic Heteroarenes Catalyzed by an Ionic Salt of a Pd Complex with an N-Heterocyclic Carbene Ligand

A new ionic salt, cis‐[Pd(L)(PPh3)(H2O)2](SO3CF3)2 (A), in which L is an amido‐functionalized N‐heterocyclic carbene (NHC) ligand, has been prepared by the salt metathesis reaction between [Pd(L)(PPh3)Cl2] and AgOTf in wet acetonitrile. It was successfully characterized by NMR spectroscopy, elementa...

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Veröffentlicht in:	European journal of organic chemistry 2015-07, Vol.2015 (19), p.4131-4142
Hauptverfasser:	Ghosh, Sanjay Kumar, Kuo, Bing-Chiuan, Chen, Hsiang-Yu, Li, Jia-Ying, Liu, Shuang-De, Lee, Hon Man
Format:	Artikel
Sprache:	eng
Schlagworte:	C-H activation Carbene ligands Crystals Homogeneous catalysis Ligands Nitrogen heterocycles Palladium
Online-Zugang:	Volltext
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