ChemInform Abstract: The Profound Effect of the Ring Size in the Electrocyclic Opening of Cyclobutene-Fused Bicyclic Systems

ChemInform Abstract: The Profound Effect of the Ring Size in the Electrocyclic Opening of Cyclobutene-Fused Bicyclic Systems

The thermolytic rearrangement of hydroxymethyl‐substituted cyclobutene diesters (I) and (III) fused to medium and large aliphatic rings yields cis‐ or trans‐cycloalkene‐fused lactones depending on the size of the annelated ring.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:ChemInform 2015-06, Vol.46 (24), p.no-no
Hauptverfasser: Ralph, Michael J., Harrowven, David C., Gaulier, Steven, Ng, Sean, Booker-Milburn, Kevin I.
Format: Artikel
Sprache:eng
Schlagworte:
amide formation
esterification
esterification, transesterification
furan derivatives
fused pyridine derivatives
fused pyrrole derivatives
ring expansion
transesterification
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The thermolytic rearrangement of hydroxymethyl‐substituted cyclobutene diesters (I) and (III) fused to medium and large aliphatic rings yields cis‐ or trans‐cycloalkene‐fused lactones depending on the size of the annelated ring.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201524038