Two New Phenylethanoid Glycosides from Callicarpa longissima

Two new phenylethanoid glycosides, longissimosides A and B (1 and 2, resp.), together with eight structurally related known compounds, were isolated from the EtOH extract of leaves and stems of Callicarpa longissima (Hemsl.) Merr. The structures of 1 and 2 were elucidated as 2‐(3,4‐dihydroxyphenyl)e...

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Veröffentlicht in:Helvetica chimica acta 2015-04, Vol.98 (4), p.482-489
Hauptverfasser: Yuan, Jing-Quan, Qiu, Li, Zou, Lu-Hui, Wei, Qian, Miao, Jian-Hua, Yao, Xin-Sheng
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container_start_page 482
container_title Helvetica chimica acta
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creator Yuan, Jing-Quan
Qiu, Li
Zou, Lu-Hui
Wei, Qian
Miao, Jian-Hua
Yao, Xin-Sheng
description Two new phenylethanoid glycosides, longissimosides A and B (1 and 2, resp.), together with eight structurally related known compounds, were isolated from the EtOH extract of leaves and stems of Callicarpa longissima (Hemsl.) Merr. The structures of 1 and 2 were elucidated as 2‐(3,4‐dihydroxyphenyl)ethyl O‐(α‐L‐rhamnopyranosyl)‐(1→3)‐O‐(2‐O‐syringoyl‐β‐D‐xylopyranosyl)‐(1→6)‐ 4‐O‐[(E)‐caffeoyl]‐β‐D‐glucopyranoside (1) and 2‐(3‐hydroxy‐4‐methoxyphenyl)ethyl O‐(α‐L‐rhamnopyranosyl)‐(1→3)‐O‐(β‐D‐apiofuranosyl)‐(1→6)‐4‐O‐[(E)‐isoferuloyl]‐β‐D‐glucopyranoside (2) on the basis of spectroscopic data and acid hydrolysis.
doi_str_mv 10.1002/hlca.201400206
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subjects Callicarpa longissima
Glycosides
Longissimosides A and B
Phenylethanoid glycosides
title Two New Phenylethanoid Glycosides from Callicarpa longissima
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