Highly Reactive Polyisobutylenes via Cationic Polymerization of Isobutylene by AlCl3/Ether Complexes in Non-Polar Media: Scope and Limitations

Summary The cationic polymerization of isobutylene using AlCl3 × OBu2 and AlCl3 × OiPr2 as co‐initiators in two non‐polar solvents (toluene and n‐hexane) at different temperatures and monomer concentrations has been investigated. In toluene, highly reactive polyisobutylene (HR PIB) with desired low...

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Veröffentlicht in:	Macromolecular symposia. 2015-03, Vol.349 (1), p.94-103
Hauptverfasser:	Kostjuk, Sergei V., Vasilenko, Irina V., Shiman, Dmitriy I., Frolov, Alexander N., Gaponik, Ludmila V.
Format:	Artikel
Sprache:	eng
Schlagworte:	cationic polymerization complexes of AlCl3 highly reactive polyisobutylene isobutylene Molecular weight Polymerization
Online-Zugang:	Volltext
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