HERON reactions of anomeric amides: understanding the driving force

Calculations show that anomeric amides, amides bearing two electronegative atoms at the amide nitrogen, are unusual in structure and reactivity. They have much reduced amide resonance and also undergo the HERON reaction where anomeric destabilisation results in migration of one substituent from nitr...

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Veröffentlicht in:	Journal of physical organic chemistry 2015-03, Vol.28 (3), p.215-222
Hauptverfasser:	Glover, Stephen A., Rosser, Adam A.
Format:	Artikel
Sprache:	eng
Schlagworte:	anomeric amides DFT calculations HERON reactions Nitrogen reaction mechanism twisted amides
Online-Zugang:	Volltext
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