Synthesis and characterization of TiO2/C Janus composite particles and its photocatalytic activity for the degradation of rhodamine B
Janus materials with anisotropic chemical structures and physical properties have attracted increasing attention due to their diversified potential applications. In this paper, titanium dioxide/3-(trimethoxysilyl) propylmethacrylate (TiO 2 /MPS) was obtained by swelling assisted with extrusion of PS...
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| Veröffentlicht in: | Colloid and polymer science 2014-12, Vol.292 (12), p.3085-3093 |
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| creator | Huang, Haibin Chen, Qinhui He, Junhui Zheng, Longhui Chen, Baoling Lin, Jinhuo |
| description | Janus materials with anisotropic chemical structures and physical properties have attracted increasing attention due to their diversified potential applications. In this paper, titanium dioxide/3-(trimethoxysilyl) propylmethacrylate (TiO
2
/MPS) was obtained by swelling assisted with extrusion of PS@TiO
2
. Then, the phenolic resin (PF) was coated on the surface of MPS lobe. Finally, TiO
2
/C Janus composite particles were obtained by sintering at the atmosphere of nitrogen. The middle objects during reactive process and the final product were systematically characterized. Results showed that the Janus porous particles of TiO
2
/C were snowman-like structure, in which the average diameter of the carbon lobe was 178 nm and that of TiO
2
lobe was 226 nm. When used as photocatalysts for Rhodamine B degradation in aqueous solution under UV irradiation, the resulted Janus product exhibited more efficient photocatalytic activity than TiO
2
hollow microspheres.
Graphical abstract
Schematic illustration of swelling polymerization approach to synthesize TiO
2
/C Janus composite particles and its photocatalytic activity for the degradation of rhodamine B |
| doi_str_mv | 10.1007/s00396-014-3362-1 |
| format | Article |
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2
/MPS) was obtained by swelling assisted with extrusion of PS@TiO
2
. Then, the phenolic resin (PF) was coated on the surface of MPS lobe. Finally, TiO
2
/C Janus composite particles were obtained by sintering at the atmosphere of nitrogen. The middle objects during reactive process and the final product were systematically characterized. Results showed that the Janus porous particles of TiO
2
/C were snowman-like structure, in which the average diameter of the carbon lobe was 178 nm and that of TiO
2
lobe was 226 nm. When used as photocatalysts for Rhodamine B degradation in aqueous solution under UV irradiation, the resulted Janus product exhibited more efficient photocatalytic activity than TiO
2
hollow microspheres.
Graphical abstract
Schematic illustration of swelling polymerization approach to synthesize TiO
2
/C Janus composite particles and its photocatalytic activity for the degradation of rhodamine B</description><identifier>ISSN: 0303-402X</identifier><identifier>EISSN: 1435-1536</identifier><identifier>DOI: 10.1007/s00396-014-3362-1</identifier><identifier>CODEN: CPMSB6</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Applied sciences ; Catalysis ; Catalysts: preparations and properties ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Composites ; Exact sciences and technology ; Food Science ; Forms of application and semi-finished materials ; General and physical chemistry ; Nanotechnology and Microengineering ; Original Contribution ; Physical Chemistry ; Polymer industry, paints, wood ; Polymer Sciences ; Soft and Granular Matter ; Technology of polymers ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><ispartof>Colloid and polymer science, 2014-12, Vol.292 (12), p.3085-3093</ispartof><rights>Springer-Verlag Berlin Heidelberg 2014</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c416t-4770f4db1aa0d7982b64c87d7ac5b91eb80d30593fe19ef6c822ea515853e6cc3</citedby><cites>FETCH-LOGICAL-c416t-4770f4db1aa0d7982b64c87d7ac5b91eb80d30593fe19ef6c822ea515853e6cc3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00396-014-3362-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00396-014-3362-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28919498$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Huang, Haibin</creatorcontrib><creatorcontrib>Chen, Qinhui</creatorcontrib><creatorcontrib>He, Junhui</creatorcontrib><creatorcontrib>Zheng, Longhui</creatorcontrib><creatorcontrib>Chen, Baoling</creatorcontrib><creatorcontrib>Lin, Jinhuo</creatorcontrib><title>Synthesis and characterization of TiO2/C Janus composite particles and its photocatalytic activity for the degradation of rhodamine B</title><title>Colloid and polymer science</title><addtitle>Colloid Polym Sci</addtitle><description>Janus materials with anisotropic chemical structures and physical properties have attracted increasing attention due to their diversified potential applications. In this paper, titanium dioxide/3-(trimethoxysilyl) propylmethacrylate (TiO
2
/MPS) was obtained by swelling assisted with extrusion of PS@TiO
2
. Then, the phenolic resin (PF) was coated on the surface of MPS lobe. Finally, TiO
2
/C Janus composite particles were obtained by sintering at the atmosphere of nitrogen. The middle objects during reactive process and the final product were systematically characterized. Results showed that the Janus porous particles of TiO
2
/C were snowman-like structure, in which the average diameter of the carbon lobe was 178 nm and that of TiO
2
lobe was 226 nm. When used as photocatalysts for Rhodamine B degradation in aqueous solution under UV irradiation, the resulted Janus product exhibited more efficient photocatalytic activity than TiO
2
hollow microspheres.
Graphical abstract
Schematic illustration of swelling polymerization approach to synthesize TiO
2
/C Janus composite particles and its photocatalytic activity for the degradation of rhodamine B</description><subject>Applied sciences</subject><subject>Catalysis</subject><subject>Catalysts: preparations and properties</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Composites</subject><subject>Exact sciences and technology</subject><subject>Food Science</subject><subject>Forms of application and semi-finished materials</subject><subject>General and physical chemistry</subject><subject>Nanotechnology and Microengineering</subject><subject>Original Contribution</subject><subject>Physical Chemistry</subject><subject>Polymer industry, paints, wood</subject><subject>Polymer Sciences</subject><subject>Soft and Granular Matter</subject><subject>Technology of polymers</subject><subject>Theory of reactions, general kinetics. Catalysis. 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Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Huang, Haibin</creatorcontrib><creatorcontrib>Chen, Qinhui</creatorcontrib><creatorcontrib>He, Junhui</creatorcontrib><creatorcontrib>Zheng, Longhui</creatorcontrib><creatorcontrib>Chen, Baoling</creatorcontrib><creatorcontrib>Lin, Jinhuo</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection (ProQuest)</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Colloid and polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Huang, Haibin</au><au>Chen, Qinhui</au><au>He, Junhui</au><au>Zheng, Longhui</au><au>Chen, Baoling</au><au>Lin, Jinhuo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and characterization of TiO2/C Janus composite particles and its photocatalytic activity for the degradation of rhodamine B</atitle><jtitle>Colloid and polymer science</jtitle><stitle>Colloid Polym Sci</stitle><date>2014-12-01</date><risdate>2014</risdate><volume>292</volume><issue>12</issue><spage>3085</spage><epage>3093</epage><pages>3085-3093</pages><issn>0303-402X</issn><eissn>1435-1536</eissn><coden>CPMSB6</coden><abstract>Janus materials with anisotropic chemical structures and physical properties have attracted increasing attention due to their diversified potential applications. In this paper, titanium dioxide/3-(trimethoxysilyl) propylmethacrylate (TiO
2
/MPS) was obtained by swelling assisted with extrusion of PS@TiO
2
. Then, the phenolic resin (PF) was coated on the surface of MPS lobe. Finally, TiO
2
/C Janus composite particles were obtained by sintering at the atmosphere of nitrogen. The middle objects during reactive process and the final product were systematically characterized. Results showed that the Janus porous particles of TiO
2
/C were snowman-like structure, in which the average diameter of the carbon lobe was 178 nm and that of TiO
2
lobe was 226 nm. When used as photocatalysts for Rhodamine B degradation in aqueous solution under UV irradiation, the resulted Janus product exhibited more efficient photocatalytic activity than TiO
2
hollow microspheres.
Graphical abstract
Schematic illustration of swelling polymerization approach to synthesize TiO
2
/C Janus composite particles and its photocatalytic activity for the degradation of rhodamine B</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00396-014-3362-1</doi><tpages>9</tpages></addata></record> |
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| subjects | Applied sciences Catalysis Catalysts: preparations and properties Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Composites Exact sciences and technology Food Science Forms of application and semi-finished materials General and physical chemistry Nanotechnology and Microengineering Original Contribution Physical Chemistry Polymer industry, paints, wood Polymer Sciences Soft and Granular Matter Technology of polymers Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
| title | Synthesis and characterization of TiO2/C Janus composite particles and its photocatalytic activity for the degradation of rhodamine B |
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