Synthesis, Characterization and Aqueous Properties of a New Hybrid Fluorocarbon Cationic Surfmer
A novel hybrid fluorocarbon cationic surfmer has been synthesized and its aggregation and surface properties have been studied by surface tension, electrical conductivity, steady-state fluorescence, Rayleigh light scattering, dynamic light scattering and transmission electron microscopy. Through sur...
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| Veröffentlicht in: | Journal of surfactants and detergents 2015-03, Vol.18 (2), p.233-244 |
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| creator | Che, YuJu Gao, Qing Fang, Meiling Tan, Yebang Wang, Xiaoli Meng, Fanjun |
| description | A novel hybrid fluorocarbon cationic surfmer has been synthesized and its aggregation and surface properties have been studied by surface tension, electrical conductivity, steady-state fluorescence, Rayleigh light scattering, dynamic light scattering and transmission electron microscopy. Through surface tension, electrical conductivity, steady-state fluorescence and Rayleigh light scattering measurements, the effectiveness of surface tension reduction, the maximum surface excess concentration, the minimum area occupied per surfactant molecule at the air/water interface, the micropolarity and aggregation number of micelles were investigated. The results shows that the surfmer has superior surface activity and lower micropolarity than other surfmers. The critical micelle concentration at different temperatures and a series of thermodynamic parameters (
Δ
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mic
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,
Δ
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) of micellization were evaluated. The thermodynamic parameters showed that the micelle formation was entropy-driven in the temperature range of 15–40 °C. The size and morphology of the aggregates were also confirmed by dynamic light scattering and transmission electron microscopy. |
| doi_str_mv | 10.1007/s11743-014-1649-3 |
| format | Article |
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Δ
G
mic
o
,
Δ
H
mic
o
, and
Δ
S
mic
o
,
Δ
G
ads
o
,
Δ
H
mic
A
, and
Δ
C
pmic
o
) of micellization were evaluated. The thermodynamic parameters showed that the micelle formation was entropy-driven in the temperature range of 15–40 °C. The size and morphology of the aggregates were also confirmed by dynamic light scattering and transmission electron microscopy.</description><identifier>ISSN: 1097-3958</identifier><identifier>EISSN: 1558-9293</identifier><identifier>DOI: 10.1007/s11743-014-1649-3</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Aggregation behaviors ; Aquatic Pollution ; Aqueous chemistry ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Fluorescence ; Industrial Chemistry/Chemical Engineering ; Light scattering ; Original Article ; Physical Chemistry ; Polymer Sciences ; Semi‐fluorinated surfactants ; Surface activity properties ; Surface tension ; Surfaces and Interfaces ; Surfactants ; Surfmers ; Synthesis ; Thin Films ; Waste Water Technology ; Water Management ; Water Pollution Control</subject><ispartof>Journal of surfactants and detergents, 2015-03, Vol.18 (2), p.233-244</ispartof><rights>AOCS 2014</rights><rights>2015 American Oil Chemists' Society (AOCS)</rights><rights>AOCS 2015</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4343-d6e9b2650234fd8e7549c4da10bcfba230ce2bd2758c9170883c0d1497f31cf3</citedby><cites>FETCH-LOGICAL-c4343-d6e9b2650234fd8e7549c4da10bcfba230ce2bd2758c9170883c0d1497f31cf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1007%2Fs11743-014-1649-3$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1007%2Fs11743-014-1649-3$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27923,27924,45573,45574</link.rule.ids></links><search><creatorcontrib>Che, YuJu</creatorcontrib><creatorcontrib>Gao, Qing</creatorcontrib><creatorcontrib>Fang, Meiling</creatorcontrib><creatorcontrib>Tan, Yebang</creatorcontrib><creatorcontrib>Wang, Xiaoli</creatorcontrib><creatorcontrib>Meng, Fanjun</creatorcontrib><title>Synthesis, Characterization and Aqueous Properties of a New Hybrid Fluorocarbon Cationic Surfmer</title><title>Journal of surfactants and detergents</title><addtitle>J Surfact Deterg</addtitle><description>A novel hybrid fluorocarbon cationic surfmer has been synthesized and its aggregation and surface properties have been studied by surface tension, electrical conductivity, steady-state fluorescence, Rayleigh light scattering, dynamic light scattering and transmission electron microscopy. Through surface tension, electrical conductivity, steady-state fluorescence and Rayleigh light scattering measurements, the effectiveness of surface tension reduction, the maximum surface excess concentration, the minimum area occupied per surfactant molecule at the air/water interface, the micropolarity and aggregation number of micelles were investigated. The results shows that the surfmer has superior surface activity and lower micropolarity than other surfmers. The critical micelle concentration at different temperatures and a series of thermodynamic parameters (
Δ
G
mic
o
,
Δ
H
mic
o
, and
Δ
S
mic
o
,
Δ
G
ads
o
,
Δ
H
mic
A
, and
Δ
C
pmic
o
) of micellization were evaluated. The thermodynamic parameters showed that the micelle formation was entropy-driven in the temperature range of 15–40 °C. The size and morphology of the aggregates were also confirmed by dynamic light scattering and transmission electron microscopy.</description><subject>Aggregation behaviors</subject><subject>Aquatic Pollution</subject><subject>Aqueous chemistry</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Fluorescence</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Light scattering</subject><subject>Original Article</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Semi‐fluorinated surfactants</subject><subject>Surface activity properties</subject><subject>Surface tension</subject><subject>Surfaces and Interfaces</subject><subject>Surfactants</subject><subject>Surfmers</subject><subject>Synthesis</subject><subject>Thin Films</subject><subject>Waste Water Technology</subject><subject>Water Management</subject><subject>Water Pollution Control</subject><issn>1097-3958</issn><issn>1558-9293</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNqFkDFPwzAQhSMEEqXwA9gssRKwYzu2xypQCqoAqd2N4zjUVRsXO1EVfj0uYWBBTHfD--69e0lyieANgpDdBoQYwSlEJEU5ESk-SkaIUp6KTODjuEPBUiwoP03OQlhDmCFC6Sh5W_RNuzLBhmtQrJRXujXefqrWugaopgKTj864LoBX73bGt9YE4GqgwLPZg1lfeluB6aZz3mnly8gU36jVYNH5emv8eXJSq00wFz9znCyn98tils5fHh6LyTzVBMfgVW5EmeUUZpjUFTeMEqFJpRAsdV2qDENtsrLKGOVaIAY5xxpWiAhWY6RrPE6uhrM772Li0Mq163wTHSXKKc0Z54JHFRpU2rsQvKnlztut8r1EUB56lEOPMvYoDz1KHBk2MHu7Mf3_gHxa3N3HNw5kNpAhQs278b8y_Wn3BY3nhkw</recordid><startdate>201503</startdate><enddate>201503</enddate><creator>Che, YuJu</creator><creator>Gao, Qing</creator><creator>Fang, Meiling</creator><creator>Tan, Yebang</creator><creator>Wang, Xiaoli</creator><creator>Meng, Fanjun</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>4T-</scope><scope>7QH</scope><scope>7UA</scope><scope>7XB</scope><scope>88I</scope><scope>8AO</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>C1K</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F1W</scope><scope>GNUQQ</scope><scope>H97</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L.G</scope><scope>M2P</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope></search><sort><creationdate>201503</creationdate><title>Synthesis, Characterization and Aqueous Properties of a New Hybrid Fluorocarbon Cationic Surfmer</title><author>Che, YuJu ; Gao, Qing ; Fang, Meiling ; Tan, Yebang ; Wang, Xiaoli ; Meng, Fanjun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4343-d6e9b2650234fd8e7549c4da10bcfba230ce2bd2758c9170883c0d1497f31cf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Aggregation behaviors</topic><topic>Aquatic Pollution</topic><topic>Aqueous chemistry</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Fluorescence</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Light scattering</topic><topic>Original Article</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Semi‐fluorinated surfactants</topic><topic>Surface activity properties</topic><topic>Surface tension</topic><topic>Surfaces and Interfaces</topic><topic>Surfactants</topic><topic>Surfmers</topic><topic>Synthesis</topic><topic>Thin Films</topic><topic>Waste Water Technology</topic><topic>Water Management</topic><topic>Water Pollution Control</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Che, YuJu</creatorcontrib><creatorcontrib>Gao, Qing</creatorcontrib><creatorcontrib>Fang, Meiling</creatorcontrib><creatorcontrib>Tan, Yebang</creatorcontrib><creatorcontrib>Wang, Xiaoli</creatorcontrib><creatorcontrib>Meng, Fanjun</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Docstoc</collection><collection>Aqualine</collection><collection>Water Resources Abstracts</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest Pharma Collection</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>ProQuest Central Student</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Science Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><jtitle>Journal of surfactants and detergents</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Che, YuJu</au><au>Gao, Qing</au><au>Fang, Meiling</au><au>Tan, Yebang</au><au>Wang, Xiaoli</au><au>Meng, Fanjun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, Characterization and Aqueous Properties of a New Hybrid Fluorocarbon Cationic Surfmer</atitle><jtitle>Journal of surfactants and detergents</jtitle><stitle>J Surfact Deterg</stitle><date>2015-03</date><risdate>2015</risdate><volume>18</volume><issue>2</issue><spage>233</spage><epage>244</epage><pages>233-244</pages><issn>1097-3958</issn><eissn>1558-9293</eissn><abstract>A novel hybrid fluorocarbon cationic surfmer has been synthesized and its aggregation and surface properties have been studied by surface tension, electrical conductivity, steady-state fluorescence, Rayleigh light scattering, dynamic light scattering and transmission electron microscopy. Through surface tension, electrical conductivity, steady-state fluorescence and Rayleigh light scattering measurements, the effectiveness of surface tension reduction, the maximum surface excess concentration, the minimum area occupied per surfactant molecule at the air/water interface, the micropolarity and aggregation number of micelles were investigated. The results shows that the surfmer has superior surface activity and lower micropolarity than other surfmers. The critical micelle concentration at different temperatures and a series of thermodynamic parameters (
Δ
G
mic
o
,
Δ
H
mic
o
, and
Δ
S
mic
o
,
Δ
G
ads
o
,
Δ
H
mic
A
, and
Δ
C
pmic
o
) of micellization were evaluated. The thermodynamic parameters showed that the micelle formation was entropy-driven in the temperature range of 15–40 °C. The size and morphology of the aggregates were also confirmed by dynamic light scattering and transmission electron microscopy.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11743-014-1649-3</doi><tpages>12</tpages></addata></record> |
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| ispartof | Journal of surfactants and detergents, 2015-03, Vol.18 (2), p.233-244 |
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| source | Wiley Online Library All Journals |
| subjects | Aggregation behaviors Aquatic Pollution Aqueous chemistry Chemical synthesis Chemistry Chemistry and Materials Science Fluorescence Industrial Chemistry/Chemical Engineering Light scattering Original Article Physical Chemistry Polymer Sciences Semi‐fluorinated surfactants Surface activity properties Surface tension Surfaces and Interfaces Surfactants Surfmers Synthesis Thin Films Waste Water Technology Water Management Water Pollution Control |
| title | Synthesis, Characterization and Aqueous Properties of a New Hybrid Fluorocarbon Cationic Surfmer |
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