From Anilines to Isatins: Oxidative Palladium-Catalyzed Double Carbonylation of CH Bonds
A novel palladium-catalyzed CH double carbonylation introduces two adjacent carbonyl groups for the synthesis of isatins from readily available anilines. The reaction proceeds under atmospheric pressure of CO with high regioselectivity and without any additives. Density functional theory investigati...
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| Veröffentlicht in: | Angewandte Chemie 2015-02, Vol.127 (6), p.1913 |
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| container_issue | 6 |
| container_start_page | 1913 |
| container_title | Angewandte Chemie |
| container_volume | 127 |
| creator | Li, Wu Duan, Zhengli Zhang, Xueye Zhang, Heng Wang, Mengfan Jiang, Ru Zeng, Hongyao Liu, Chao Lei, Aiwen |
| description | A novel palladium-catalyzed CH double carbonylation introduces two adjacent carbonyl groups for the synthesis of isatins from readily available anilines. The reaction proceeds under atmospheric pressure of CO with high regioselectivity and without any additives. Density functional theory investigations indicate that the palladium-catalyzed double carbonylation catalytic cycle is plausible. |
| doi_str_mv | 10.1002/ange.201410321 |
| format | Article |
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| issn | 0044-8249 1521-3757 |
| language | ger |
| recordid | cdi_proquest_journals_1650135326 |
| source | Wiley Online Library All Journals |
| subjects | Chemistry |
| title | From Anilines to Isatins: Oxidative Palladium-Catalyzed Double Carbonylation of CH Bonds |
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