Copper(II)-Promoted C-C Bond Formation by Oxidative Coupling of Two C(sp3)-H Bonds Adjacent to Carbonyl Group to Construct 1,4-Diketones and Tetrasubstituted Furans
The copper(II)‐promoted C–C bond formation from the coupling of two C(sp3)–H bonds that are adjacent to a carbonyl group was achieved. This protocol offers a simple and efficient approach to 2,3‐disubstituted 1,4‐diketones and tetrasubstituted furans. This method features a wide substrate scope and...
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| Veröffentlicht in: | European journal of organic chemistry 2015-02, Vol.2015 (4), p.876-885 |
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| container_end_page | 885 |
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| container_issue | 4 |
| container_start_page | 876 |
| container_title | European journal of organic chemistry |
| container_volume | 2015 |
| creator | Mao, Shuai Gao, Ya-Ru Zhang, Shao-Liang Guo, Dong-Dong Wang, Yong-Qiang |
| description | The copper(II)‐promoted C–C bond formation from the coupling of two C(sp3)–H bonds that are adjacent to a carbonyl group was achieved. This protocol offers a simple and efficient approach to 2,3‐disubstituted 1,4‐diketones and tetrasubstituted furans. This method features a wide substrate scope and high functional group tolerance.
Coupling of two C–H bonds adjacent to a carbonyl group: The copper(II)‐promoted coupling of two C(sp3)–H bonds that are adjacent to a carbonyl group was carried out for the preparation of 2,3‐disubstituted 1,4‐diketones and tetrasubstituted furans. This economic approach features a wide substrate scope and a high functional group tolerance. |
| doi_str_mv | 10.1002/ejoc.201403274 |
| format | Article |
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Coupling of two C–H bonds adjacent to a carbonyl group: The copper(II)‐promoted coupling of two C(sp3)–H bonds that are adjacent to a carbonyl group was carried out for the preparation of 2,3‐disubstituted 1,4‐diketones and tetrasubstituted furans. This economic approach features a wide substrate scope and a high functional group tolerance.</description><identifier>ISSN: 1434-193X</identifier><identifier>EISSN: 1099-0690</identifier><identifier>DOI: 10.1002/ejoc.201403274</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>C-C coupling ; Copper ; Oxidation ; Oxygen heterocycles ; Synthetic methods</subject><ispartof>European journal of organic chemistry, 2015-02, Vol.2015 (4), p.876-885</ispartof><rights>Copyright © 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4214-715f3f61a1f798d747090c2a5900f3eb527729a08f820edf7b8b7474297240d03</citedby><cites>FETCH-LOGICAL-c4214-715f3f61a1f798d747090c2a5900f3eb527729a08f820edf7b8b7474297240d03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fejoc.201403274$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fejoc.201403274$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Mao, Shuai</creatorcontrib><creatorcontrib>Gao, Ya-Ru</creatorcontrib><creatorcontrib>Zhang, Shao-Liang</creatorcontrib><creatorcontrib>Guo, Dong-Dong</creatorcontrib><creatorcontrib>Wang, Yong-Qiang</creatorcontrib><title>Copper(II)-Promoted C-C Bond Formation by Oxidative Coupling of Two C(sp3)-H Bonds Adjacent to Carbonyl Group to Construct 1,4-Diketones and Tetrasubstituted Furans</title><title>European journal of organic chemistry</title><addtitle>Eur. J. Org. Chem</addtitle><description>The copper(II)‐promoted C–C bond formation from the coupling of two C(sp3)–H bonds that are adjacent to a carbonyl group was achieved. This protocol offers a simple and efficient approach to 2,3‐disubstituted 1,4‐diketones and tetrasubstituted furans. This method features a wide substrate scope and high functional group tolerance.
Coupling of two C–H bonds adjacent to a carbonyl group: The copper(II)‐promoted coupling of two C(sp3)–H bonds that are adjacent to a carbonyl group was carried out for the preparation of 2,3‐disubstituted 1,4‐diketones and tetrasubstituted furans. This economic approach features a wide substrate scope and a high functional group tolerance.</description><subject>C-C coupling</subject><subject>Copper</subject><subject>Oxidation</subject><subject>Oxygen heterocycles</subject><subject>Synthetic methods</subject><issn>1434-193X</issn><issn>1099-0690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqFkU1vEzEQhlcIJErhytkSl1bC6fhj7fhYliZNVZFKDYKb5d210aaJvbW9tPk__NBuGlRx4zRf7zMz0lsUHwlMCAA9s-vQTCgQDoxK_qo4IqAUBqHg9ZhzxjFR7Ofb4l1KawBQQpCj4k8V-t7Gk8XiFN_EsA3ZtqjCFfoSfItmIW5N7oJH9Q4tH7t2LH5bVIWh33T-FwoOrR4Cqk5Sz07x5TOU0Hm7No31GeVxZGId_G6D5nGEnjvBpxyHJiPymeOv3Z3NwduEzHhvZXM0aahT7vKw_2Q2ROPT--KNM5tkP_yNx8X32cWqusTXy_miOr_GDaeEY0lKx5wghjippq3kEhQ01JQKwDFbl1RKqgxM3ZSCbZ2sp_Uo4lRJyqEFdlx8OuztY7gfbMp6HYbox5OaCC6UkLTcqyYHVRNDStE63cdua-JOE9B7J_TeCf3ixAioA_DQbezuP2p9cbWs_mXxge1Sto8vrIl3WkgmS_3j21zTqxm_vRG3esWeANmnmyU</recordid><startdate>201502</startdate><enddate>201502</enddate><creator>Mao, Shuai</creator><creator>Gao, Ya-Ru</creator><creator>Zhang, Shao-Liang</creator><creator>Guo, Dong-Dong</creator><creator>Wang, Yong-Qiang</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201502</creationdate><title>Copper(II)-Promoted C-C Bond Formation by Oxidative Coupling of Two C(sp3)-H Bonds Adjacent to Carbonyl Group to Construct 1,4-Diketones and Tetrasubstituted Furans</title><author>Mao, Shuai ; Gao, Ya-Ru ; Zhang, Shao-Liang ; Guo, Dong-Dong ; Wang, Yong-Qiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4214-715f3f61a1f798d747090c2a5900f3eb527729a08f820edf7b8b7474297240d03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>C-C coupling</topic><topic>Copper</topic><topic>Oxidation</topic><topic>Oxygen heterocycles</topic><topic>Synthetic methods</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mao, Shuai</creatorcontrib><creatorcontrib>Gao, Ya-Ru</creatorcontrib><creatorcontrib>Zhang, Shao-Liang</creatorcontrib><creatorcontrib>Guo, Dong-Dong</creatorcontrib><creatorcontrib>Wang, Yong-Qiang</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>European journal of organic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mao, Shuai</au><au>Gao, Ya-Ru</au><au>Zhang, Shao-Liang</au><au>Guo, Dong-Dong</au><au>Wang, Yong-Qiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Copper(II)-Promoted C-C Bond Formation by Oxidative Coupling of Two C(sp3)-H Bonds Adjacent to Carbonyl Group to Construct 1,4-Diketones and Tetrasubstituted Furans</atitle><jtitle>European journal of organic chemistry</jtitle><addtitle>Eur. J. Org. Chem</addtitle><date>2015-02</date><risdate>2015</risdate><volume>2015</volume><issue>4</issue><spage>876</spage><epage>885</epage><pages>876-885</pages><issn>1434-193X</issn><eissn>1099-0690</eissn><abstract>The copper(II)‐promoted C–C bond formation from the coupling of two C(sp3)–H bonds that are adjacent to a carbonyl group was achieved. This protocol offers a simple and efficient approach to 2,3‐disubstituted 1,4‐diketones and tetrasubstituted furans. This method features a wide substrate scope and high functional group tolerance.
Coupling of two C–H bonds adjacent to a carbonyl group: The copper(II)‐promoted coupling of two C(sp3)–H bonds that are adjacent to a carbonyl group was carried out for the preparation of 2,3‐disubstituted 1,4‐diketones and tetrasubstituted furans. This economic approach features a wide substrate scope and a high functional group tolerance.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/ejoc.201403274</doi><tpages>10</tpages></addata></record> |
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| ispartof | European journal of organic chemistry, 2015-02, Vol.2015 (4), p.876-885 |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | C-C coupling Copper Oxidation Oxygen heterocycles Synthetic methods |
| title | Copper(II)-Promoted C-C Bond Formation by Oxidative Coupling of Two C(sp3)-H Bonds Adjacent to Carbonyl Group to Construct 1,4-Diketones and Tetrasubstituted Furans |
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