Remote meta-CH Olefination of Phenylacetic Acids Directed by a Versatile U-Shaped Template

meta-CH olefination of phenylacetic acid derivatives has been achieved using a commercially available nitrile-containing template. The identification of N-formyl-protected glycine as the ligand (Formyl-Gly-OH) was crucial for the development of this reaction. Versatility of the template approach in...

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Veröffentlicht in:	Angewandte Chemie International Edition 2015-01, Vol.54 (3), p.888
Hauptverfasser:	Deng, Youqian, Yu, Jin-Quan
Format:	Artikel
Sprache:	eng
Schlagworte:	Acids
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description	meta-CH olefination of phenylacetic acid derivatives has been achieved using a commercially available nitrile-containing template. The identification of N-formyl-protected glycine as the ligand (Formyl-Gly-OH) was crucial for the development of this reaction. Versatility of the template approach in accommodating macrocyclopalladation processes with different ring sizes is demonstrated.
doi_str_mv	10.1002/anie.201409860
format	Article
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subjects	Acids
title	Remote meta-CH Olefination of Phenylacetic Acids Directed by a Versatile U-Shaped Template
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