ChemInform Abstract: Enantioselective Cascade Formal Reductive Insertion of Allylic Alcohols into the C(O)-C Bond of 1,3-Diketones: Ready Access to Synthetically Valuable 3-Alkylpentanol Units
Functionalized γ‐chiral alcohols are prepared via an unprecedented cascade reaction which combines dual iron—amine‐catalyzed enantioselective functionalization of allylic alcohols and chemoselective acyl transfer.
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| Veröffentlicht in: | ChemInform 2014-12, Vol.45 (48), p.no-no |
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| container_title | ChemInform |
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| creator | Roudier, Mylene Constantieux, Thierry Quintard, Adrien Rodriguez, Jean |
| description | Functionalized γ‐chiral alcohols are prepared via an unprecedented cascade reaction which combines dual iron—amine‐catalyzed enantioselective functionalization of allylic alcohols and chemoselective acyl transfer. |
| doi_str_mv | 10.1002/chin.201448022 |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 0931-7597 |
| ispartof | ChemInform, 2014-12, Vol.45 (48), p.no-no |
| issn | 0931-7597 1522-2667 |
| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | C-C bond formation catalysis catalysis, phase‐transfer catalysis diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) insertion reactions phase-transfer catalysis |
| title | ChemInform Abstract: Enantioselective Cascade Formal Reductive Insertion of Allylic Alcohols into the C(O)-C Bond of 1,3-Diketones: Ready Access to Synthetically Valuable 3-Alkylpentanol Units |
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