Quasicatalytic and catalytic oxidation of methane to methanol by nitrous oxide over FeZSM-5 zeolite

•CH4 oxidation by N2O was studied in quasicatalytic and catalytic modes.•The reaction in both modes proceeds with participation of α-oxygen.•In quasicatalytic mode methanol and dimethyl ether are extracted from the surface.•In catalytic reaction mode, water strongly increases selectivity for methano...

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Veröffentlicht in:	Journal of catalysis 2014-10, Vol.318, p.14-21
Hauptverfasser:	Parfenov, Mikhail V., Starokon, Eugeny V., Pirutko, Larisa V., Panov, Gennady I.
Format:	Artikel
Sprache:	eng
Schlagworte:	Biomimetic oxidation Catalysis Catalytic oxidation Chemical reactions FeZSM-5 zeolite Methane Methane oxidation Methane to methanol Methanol N2O oxidant Nitrous oxide Product extraction Quasicatalytic reaction Surface diffusion α-Oxygen
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