Tuning acid–base cooperativity to create next generation silica-supported organocatalysts

Incorporating bio-inspired acid-base cooperative design features into heterogeneous catalysts by understanding how to select acid-base pairs and to control the distance between acid-base pairs. [Display omitted] •Controlling acid–base interactions is important in design of cooperative catalysts.•Hom...

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Veröffentlicht in:	Journal of catalysis 2013-12, Vol.308, p.60-72
Hauptverfasser:	Brunelli, Nicholas A., Jones, Christopher W.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acids Aldol condensation amines Catalysis Catalyst design catalysts catalytic activity Chemistry condensation Cooperative catalysis Exact sciences and technology General and physical chemistry Linker length Nitroaldol condensation Organocatalysis porosity Silanol silica Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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