A Magnetically Separable Catalyst for Synthesis of 1-Phenoxy-2-propanol Via Atom-economic Reaction
A magnetically separable catalyst Al2O3‐MgO/Fe3O4 was prepared by Al2O3‐MgO supported on magnetic oxide Fe3O4 and charactered by FT‐IR, XRD and SEM. The mixed oxides afforded high catalytic activity and selectivity for synthesis of 1‐phenoxy‐2‐propanol from phenol and propylene oxide with 80.3% conv...
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| Veröffentlicht in: | Journal of the Chinese Chemical Society (Taipei) 2014-10, Vol.61 (10), p.1084-1088 |
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| container_title | Journal of the Chinese Chemical Society (Taipei) |
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| creator | Feng, Shide Cao, Fengyun Lu, Bin Cai, Qinghai |
| description | A magnetically separable catalyst Al2O3‐MgO/Fe3O4 was prepared by Al2O3‐MgO supported on magnetic oxide Fe3O4 and charactered by FT‐IR, XRD and SEM. The mixed oxides afforded high catalytic activity and selectivity for synthesis of 1‐phenoxy‐2‐propanol from phenol and propylene oxide with 80.3% conversion and 88.1% selectivity to 1‐phenoxy‐2‐propanol. Especially, facile separation of the catalyst by a magnet was obtained and the catalytic performance of the recovered catalyst was unaffected even at the forth run.
A magnetically separable catalyst Al2O3‐MgO/Fe3O4 was prepared by Al2O3‐MgO supported on magnetic oxide Fe3O4 . The mixed oxides afforded high catalytic activity and selectivity for synthesis of 1‐phenoxy‐2‐propanol from phenol and propylene oxide. The facile separation and reusability of the catalyst was achieved. |
| doi_str_mv | 10.1002/jccs.201300622 |
| format | Article |
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A magnetically separable catalyst Al2O3‐MgO/Fe3O4 was prepared by Al2O3‐MgO supported on magnetic oxide Fe3O4 . The mixed oxides afforded high catalytic activity and selectivity for synthesis of 1‐phenoxy‐2‐propanol from phenol and propylene oxide. The facile separation and reusability of the catalyst was achieved.</description><identifier>ISSN: 0009-4536</identifier><identifier>EISSN: 2192-6549</identifier><identifier>DOI: 10.1002/jccs.201300622</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>1-Phenoxy-2-propanol ; Atom economy ; Magnetic separable catalyst ; Propanediol phenyl ether ; Propylene oxide</subject><ispartof>Journal of the Chinese Chemical Society (Taipei), 2014-10, Vol.61 (10), p.1084-1088</ispartof><rights>Copyright © 2014 The Chemical Society Located in Taipei & Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim, Germany</rights><rights>Copyright © 2014 The Chemical Society Located in Taipei & Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4622-cf0d8d664ac1a6854491f01159e1c1f4e20408dd1d357f6c68d3c098503b32bb3</citedby><cites>FETCH-LOGICAL-c4622-cf0d8d664ac1a6854491f01159e1c1f4e20408dd1d357f6c68d3c098503b32bb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fjccs.201300622$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fjccs.201300622$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Feng, Shide</creatorcontrib><creatorcontrib>Cao, Fengyun</creatorcontrib><creatorcontrib>Lu, Bin</creatorcontrib><creatorcontrib>Cai, Qinghai</creatorcontrib><title>A Magnetically Separable Catalyst for Synthesis of 1-Phenoxy-2-propanol Via Atom-economic Reaction</title><title>Journal of the Chinese Chemical Society (Taipei)</title><addtitle>Jnl Chinese Chemical Soc</addtitle><description>A magnetically separable catalyst Al2O3‐MgO/Fe3O4 was prepared by Al2O3‐MgO supported on magnetic oxide Fe3O4 and charactered by FT‐IR, XRD and SEM. The mixed oxides afforded high catalytic activity and selectivity for synthesis of 1‐phenoxy‐2‐propanol from phenol and propylene oxide with 80.3% conversion and 88.1% selectivity to 1‐phenoxy‐2‐propanol. Especially, facile separation of the catalyst by a magnet was obtained and the catalytic performance of the recovered catalyst was unaffected even at the forth run.
A magnetically separable catalyst Al2O3‐MgO/Fe3O4 was prepared by Al2O3‐MgO supported on magnetic oxide Fe3O4 . The mixed oxides afforded high catalytic activity and selectivity for synthesis of 1‐phenoxy‐2‐propanol from phenol and propylene oxide. The facile separation and reusability of the catalyst was achieved.</description><subject>1-Phenoxy-2-propanol</subject><subject>Atom economy</subject><subject>Magnetic separable catalyst</subject><subject>Propanediol phenyl ether</subject><subject>Propylene oxide</subject><issn>0009-4536</issn><issn>2192-6549</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqFkEtPGzEUha2KSg20W9aWWDtcPzNeRqOSgng0JG0RG8vj8ZBJJ-PUngjm3zMoVcSO1d2c79yjD6FTCmMKwM7XzqUxA8oBFGOf0IhRzYiSQh-hEQBoIiRXX9BxSmsAwZnUI1RM8Y19an1XO9s0PV74rY22aDzObWebPnW4ChEv-rZb-VQnHCpMyc-Vb8NLTxjZxrC1bWjw79riaRc2xLvQhk3t8L23rqtD-xV9rmyT_Lf_9wT9uvi-zH-Q67vZZT69Jk4Me4mroMxKpYR11KpMCqFpBZRK7amjlfAMBGRlSUsuJ5VyKiu5A51J4AVnRcFP0Nm-d9j0b-dTZ9ZhF9vhpaFyKAShQQ-p8T7lYkgp-spsY72xsTcUzJtH8-bRHDwOgN4Dz3Xj-w_S5irPF-9Zsmfr1PmXA2vjX6MmfCLNn9uZWc71w5w_SvPIXwF5sIVy</recordid><startdate>201410</startdate><enddate>201410</enddate><creator>Feng, Shide</creator><creator>Cao, Fengyun</creator><creator>Lu, Bin</creator><creator>Cai, Qinghai</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201410</creationdate><title>A Magnetically Separable Catalyst for Synthesis of 1-Phenoxy-2-propanol Via Atom-economic Reaction</title><author>Feng, Shide ; Cao, Fengyun ; Lu, Bin ; Cai, Qinghai</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4622-cf0d8d664ac1a6854491f01159e1c1f4e20408dd1d357f6c68d3c098503b32bb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>1-Phenoxy-2-propanol</topic><topic>Atom economy</topic><topic>Magnetic separable catalyst</topic><topic>Propanediol phenyl ether</topic><topic>Propylene oxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Feng, Shide</creatorcontrib><creatorcontrib>Cao, Fengyun</creatorcontrib><creatorcontrib>Lu, Bin</creatorcontrib><creatorcontrib>Cai, Qinghai</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Journal of the Chinese Chemical Society (Taipei)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Feng, Shide</au><au>Cao, Fengyun</au><au>Lu, Bin</au><au>Cai, Qinghai</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Magnetically Separable Catalyst for Synthesis of 1-Phenoxy-2-propanol Via Atom-economic Reaction</atitle><jtitle>Journal of the Chinese Chemical Society (Taipei)</jtitle><addtitle>Jnl Chinese Chemical Soc</addtitle><date>2014-10</date><risdate>2014</risdate><volume>61</volume><issue>10</issue><spage>1084</spage><epage>1088</epage><pages>1084-1088</pages><issn>0009-4536</issn><eissn>2192-6549</eissn><abstract>A magnetically separable catalyst Al2O3‐MgO/Fe3O4 was prepared by Al2O3‐MgO supported on magnetic oxide Fe3O4 and charactered by FT‐IR, XRD and SEM. The mixed oxides afforded high catalytic activity and selectivity for synthesis of 1‐phenoxy‐2‐propanol from phenol and propylene oxide with 80.3% conversion and 88.1% selectivity to 1‐phenoxy‐2‐propanol. Especially, facile separation of the catalyst by a magnet was obtained and the catalytic performance of the recovered catalyst was unaffected even at the forth run.
A magnetically separable catalyst Al2O3‐MgO/Fe3O4 was prepared by Al2O3‐MgO supported on magnetic oxide Fe3O4 . The mixed oxides afforded high catalytic activity and selectivity for synthesis of 1‐phenoxy‐2‐propanol from phenol and propylene oxide. The facile separation and reusability of the catalyst was achieved.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/jccs.201300622</doi><tpages>5</tpages></addata></record> |
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| subjects | 1-Phenoxy-2-propanol Atom economy Magnetic separable catalyst Propanediol phenyl ether Propylene oxide |
| title | A Magnetically Separable Catalyst for Synthesis of 1-Phenoxy-2-propanol Via Atom-economic Reaction |
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