Synthesis of 4,5-Dihydrofuran-3-carbonitrile Derivatives with Electron-Rich Alkenes in the Presence of Manganese(III) Acetate

Radical cyclization reactions mediated by manganese(III) acetate were carried out with ν‐excessive alkenes (2a‐d) and 3‐oxopropanenitriles (1a‐f) resulting in the formation of 3‐cyano‐4,5‐dihydrofuran derivatives in poor to high yields. A mechanism was proposed for the cyclization reaction. The sign...

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Veröffentlicht in:	Journal of the Chinese Chemical Society (Taipei) 2014-10, Vol.61 (10), p.1101-1107
Hauptverfasser:	Yllmaz, Mehmet, Burgaz, E. Vildan, Yakut, Mehtap, Biçer, Emre
Format:	Artikel
Sprache:	eng
Schlagworte:	3-Cyano-4 3-Oxopropanenitrile 3‐Cyano‐4,5‐dihydrofuran 5-dihydrofuran Derivatives Manganese(III) Radical cyclization
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