Plasma Polymerization Modified Polyvinylidene Fluoride (PVDF) Membrane Development and Characterization for Degumming of Soybean Oil
Unmodified and surface-modified polyvinylidene fluoride (PVDF) membranes were tested for their ability to degum soybean crude oil and crude oil miscellas. The membrane was modified with 1,1,1,3,3,3-hexafluoro-2-propanol or hexamethyldisiloxane (HMDSO) by radio-frequency plasma polymerization at 10–1...
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| Veröffentlicht in: | Journal of the American Oil Chemists' Society 2014-10, Vol.91 (10), p.1813-1822 |
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| creator | Onal-Ulusoy, Baran Tur, Eren Akdoğan, Ebru Mutlu, Mehmet |
| description | Unmodified and surface-modified polyvinylidene fluoride (PVDF) membranes were tested for their ability to degum soybean crude oil and crude oil miscellas. The membrane was modified with 1,1,1,3,3,3-hexafluoro-2-propanol or hexamethyldisiloxane (HMDSO) by radio-frequency plasma polymerization at 10–100 W glow discharge power and 1–30 min contact time. The membranes were characterized by contact angle measurements, attenuated total reflectance Fourier transform infrared spectroscopy, atomic force microscopy, and scanning electron microscopy. Modification of the PVDF membrane with HMDSO at 60 W power for 5 min increased the interfacial free energy between water and solid surface from 30 ± 2 to 64 ± 2 mJ/m². This membrane was tested for permeate flux and phospholipid rejection with crude oil and different concentrations of miscella. Although formation of the polymer film on the membrane tended to decrease membrane pore size, the modified membrane had an oil flux as good as the unmodified membrane did. In addition, the modified-membrane improved the phospholipid rejection and removed 76 % of the phospholipids from the crude oil and 81–90 % of the phospholipids from crude oil miscellas. |
| doi_str_mv | 10.1007/s11746-014-2522-2 |
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The membrane was modified with 1,1,1,3,3,3-hexafluoro-2-propanol or hexamethyldisiloxane (HMDSO) by radio-frequency plasma polymerization at 10–100 W glow discharge power and 1–30 min contact time. The membranes were characterized by contact angle measurements, attenuated total reflectance Fourier transform infrared spectroscopy, atomic force microscopy, and scanning electron microscopy. Modification of the PVDF membrane with HMDSO at 60 W power for 5 min increased the interfacial free energy between water and solid surface from 30 ± 2 to 64 ± 2 mJ/m². This membrane was tested for permeate flux and phospholipid rejection with crude oil and different concentrations of miscella. Although formation of the polymer film on the membrane tended to decrease membrane pore size, the modified membrane had an oil flux as good as the unmodified membrane did. In addition, the modified-membrane improved the phospholipid rejection and removed 76 % of the phospholipids from the crude oil and 81–90 % of the phospholipids from crude oil miscellas.</description><identifier>ISSN: 0003-021X</identifier><identifier>EISSN: 1558-9331</identifier><identifier>DOI: 10.1007/s11746-014-2522-2</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer-Verlag</publisher><subject>Agriculture ; atomic force microscopy ; Biomaterials ; Biotechnology ; Chemistry ; Chemistry and Materials Science ; contact angle ; Crude oil ; Degumming ; energy ; Food Science ; Fourier transform infrared spectroscopy ; Fourier transforms ; Industrial Chemistry/Chemical Engineering ; Infrared spectroscopy ; Lipids ; Membranes ; Original Paper ; Phospholipids ; Plasma modified Polyvinylidene fluoride (PVDF) ; Polymerization ; Polymers ; Pore size ; reflectance ; scanning electron microscopy ; Soybean crude oil‐hexane miscella ; Soybean oil ; Soybeans ; Ultrafiltration membrane separation ; Vegetable oils</subject><ispartof>Journal of the American Oil Chemists' Society, 2014-10, Vol.91 (10), p.1813-1822</ispartof><rights>AOCS 2014</rights><rights>2014 American Oil Chemists' Society (AOCS)</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4583-a450c701140131ec26011fd0a433ea7ed3dc9fc8c4d6d02e39d82b881fcd5ce43</citedby><cites>FETCH-LOGICAL-c4583-a450c701140131ec26011fd0a433ea7ed3dc9fc8c4d6d02e39d82b881fcd5ce43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11746-014-2522-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11746-014-2522-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,41488,42557,45574,45575,51319</link.rule.ids></links><search><creatorcontrib>Onal-Ulusoy, Baran</creatorcontrib><creatorcontrib>Tur, Eren</creatorcontrib><creatorcontrib>Akdoğan, Ebru</creatorcontrib><creatorcontrib>Mutlu, Mehmet</creatorcontrib><title>Plasma Polymerization Modified Polyvinylidene Fluoride (PVDF) Membrane Development and Characterization for Degumming of Soybean Oil</title><title>Journal of the American Oil Chemists' Society</title><addtitle>J Am Oil Chem Soc</addtitle><description>Unmodified and surface-modified polyvinylidene fluoride (PVDF) membranes were tested for their ability to degum soybean crude oil and crude oil miscellas. The membrane was modified with 1,1,1,3,3,3-hexafluoro-2-propanol or hexamethyldisiloxane (HMDSO) by radio-frequency plasma polymerization at 10–100 W glow discharge power and 1–30 min contact time. The membranes were characterized by contact angle measurements, attenuated total reflectance Fourier transform infrared spectroscopy, atomic force microscopy, and scanning electron microscopy. Modification of the PVDF membrane with HMDSO at 60 W power for 5 min increased the interfacial free energy between water and solid surface from 30 ± 2 to 64 ± 2 mJ/m². This membrane was tested for permeate flux and phospholipid rejection with crude oil and different concentrations of miscella. Although formation of the polymer film on the membrane tended to decrease membrane pore size, the modified membrane had an oil flux as good as the unmodified membrane did. In addition, the modified-membrane improved the phospholipid rejection and removed 76 % of the phospholipids from the crude oil and 81–90 % of the phospholipids from crude oil miscellas.</description><subject>Agriculture</subject><subject>atomic force microscopy</subject><subject>Biomaterials</subject><subject>Biotechnology</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>contact angle</subject><subject>Crude oil</subject><subject>Degumming</subject><subject>energy</subject><subject>Food Science</subject><subject>Fourier transform infrared spectroscopy</subject><subject>Fourier transforms</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Infrared spectroscopy</subject><subject>Lipids</subject><subject>Membranes</subject><subject>Original Paper</subject><subject>Phospholipids</subject><subject>Plasma modified Polyvinylidene fluoride (PVDF)</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Pore size</subject><subject>reflectance</subject><subject>scanning electron microscopy</subject><subject>Soybean crude oil‐hexane miscella</subject><subject>Soybean oil</subject><subject>Soybeans</subject><subject>Ultrafiltration membrane separation</subject><subject>Vegetable 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Polymerization Modified Polyvinylidene Fluoride (PVDF) Membrane Development and Characterization for Degumming of Soybean Oil</title><author>Onal-Ulusoy, Baran ; Tur, Eren ; Akdoğan, Ebru ; Mutlu, Mehmet</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4583-a450c701140131ec26011fd0a433ea7ed3dc9fc8c4d6d02e39d82b881fcd5ce43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Agriculture</topic><topic>atomic force microscopy</topic><topic>Biomaterials</topic><topic>Biotechnology</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>contact angle</topic><topic>Crude oil</topic><topic>Degumming</topic><topic>energy</topic><topic>Food Science</topic><topic>Fourier transform infrared spectroscopy</topic><topic>Fourier transforms</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Infrared spectroscopy</topic><topic>Lipids</topic><topic>Membranes</topic><topic>Original Paper</topic><topic>Phospholipids</topic><topic>Plasma modified Polyvinylidene fluoride (PVDF)</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Pore size</topic><topic>reflectance</topic><topic>scanning electron microscopy</topic><topic>Soybean crude oil‐hexane miscella</topic><topic>Soybean oil</topic><topic>Soybeans</topic><topic>Ultrafiltration membrane separation</topic><topic>Vegetable oils</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Onal-Ulusoy, Baran</creatorcontrib><creatorcontrib>Tur, Eren</creatorcontrib><creatorcontrib>Akdoğan, Ebru</creatorcontrib><creatorcontrib>Mutlu, Mehmet</creatorcontrib><collection>AGRIS</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Docstoc</collection><collection>Agricultural Science Collection</collection><collection>Health & Medical 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Chemists' Society</jtitle><stitle>J Am Oil Chem Soc</stitle><date>2014-10</date><risdate>2014</risdate><volume>91</volume><issue>10</issue><spage>1813</spage><epage>1822</epage><pages>1813-1822</pages><issn>0003-021X</issn><eissn>1558-9331</eissn><abstract>Unmodified and surface-modified polyvinylidene fluoride (PVDF) membranes were tested for their ability to degum soybean crude oil and crude oil miscellas. The membrane was modified with 1,1,1,3,3,3-hexafluoro-2-propanol or hexamethyldisiloxane (HMDSO) by radio-frequency plasma polymerization at 10–100 W glow discharge power and 1–30 min contact time. The membranes were characterized by contact angle measurements, attenuated total reflectance Fourier transform infrared spectroscopy, atomic force microscopy, and scanning electron microscopy. Modification of the PVDF membrane with HMDSO at 60 W power for 5 min increased the interfacial free energy between water and solid surface from 30 ± 2 to 64 ± 2 mJ/m². This membrane was tested for permeate flux and phospholipid rejection with crude oil and different concentrations of miscella. Although formation of the polymer film on the membrane tended to decrease membrane pore size, the modified membrane had an oil flux as good as the unmodified membrane did. In addition, the modified-membrane improved the phospholipid rejection and removed 76 % of the phospholipids from the crude oil and 81–90 % of the phospholipids from crude oil miscellas.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer-Verlag</pub><doi>10.1007/s11746-014-2522-2</doi><tpages>10</tpages></addata></record> |
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| subjects | Agriculture atomic force microscopy Biomaterials Biotechnology Chemistry Chemistry and Materials Science contact angle Crude oil Degumming energy Food Science Fourier transform infrared spectroscopy Fourier transforms Industrial Chemistry/Chemical Engineering Infrared spectroscopy Lipids Membranes Original Paper Phospholipids Plasma modified Polyvinylidene fluoride (PVDF) Polymerization Polymers Pore size reflectance scanning electron microscopy Soybean crude oil‐hexane miscella Soybean oil Soybeans Ultrafiltration membrane separation Vegetable oils |
| title | Plasma Polymerization Modified Polyvinylidene Fluoride (PVDF) Membrane Development and Characterization for Degumming of Soybean Oil |
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