Oxidation Behavior of SiC Whiskers at 600-1400°C in Air

The oxidation behavior of SiC whiskers (SiCW) with a diameter size of 50–200 nm has been investigated at 600°C–1400°C in air. Experimental results reveal that SiCW exhibit a low oxidation rate below 1100°C while a significant larger oxidation rate after that. This can be attributed to the small diam...

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Veröffentlicht in:Journal of the American Ceramic Society 2014-09, Vol.97 (9), p.2698-2701
Hauptverfasser: Kuang, Jianlei, Cao, Wenbin
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Cao, Wenbin
description The oxidation behavior of SiC whiskers (SiCW) with a diameter size of 50–200 nm has been investigated at 600°C–1400°C in air. Experimental results reveal that SiCW exhibit a low oxidation rate below 1100°C while a significant larger oxidation rate after that. This can be attributed to the small diameter size of SiCW, which determines that it is hard to form a protective SiO2 layer thick enough to hamper the diffusion of oxygen effectively. Both nonisothermal and isothermal oxidation kinetics were studied and the apparent oxidation energy was calculated to further understand the oxidation behavior of the SiCW.
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Experimental results reveal that SiCW exhibit a low oxidation rate below 1100°C while a significant larger oxidation rate after that. This can be attributed to the small diameter size of SiCW, which determines that it is hard to form a protective SiO2 layer thick enough to hamper the diffusion of oxygen effectively. 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source Wiley Online Library Journals Frontfile Complete
subjects Ceramics
Diffusion
Oxidation
Oxygen
Reaction kinetics
Silicon carbide
Temperature effects
title Oxidation Behavior of SiC Whiskers at 600-1400°C in Air
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